Conductometric Determination of Sulfhydryl Groups in Swollen Polycaprolactam Fibers Having Disulfide and Alkylene Sulfide Crosslinks

A simple conductometric titration method is discussed for the determination of sulfhydryl groups in nonionic polymer networks, such as disulfide and alkylene sulfide crosslinked polycaprolactam fibers. The diffusion of the titrant into the crosslinked polymer is accomplished by swelling the network...

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Detalles Bibliográficos
Autores principales: Bruck, Stephen D., Bailey, Sylvia M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1962
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5315335/
http://dx.doi.org/10.6028/jres.066A.017
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author Bruck, Stephen D.
Bailey, Sylvia M.
author_facet Bruck, Stephen D.
Bailey, Sylvia M.
author_sort Bruck, Stephen D.
collection PubMed
description A simple conductometric titration method is discussed for the determination of sulfhydryl groups in nonionic polymer networks, such as disulfide and alkylene sulfide crosslinked polycaprolactam fibers. The diffusion of the titrant into the crosslinked polymer is accomplished by swelling the network structure, thereby eliminating the necessity of destroying the crosslinks and/or breaking the polymer chains.
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spelling pubmed-53153352023-06-15 Conductometric Determination of Sulfhydryl Groups in Swollen Polycaprolactam Fibers Having Disulfide and Alkylene Sulfide Crosslinks Bruck, Stephen D. Bailey, Sylvia M. J Res Natl Bur Stand A Phys Chem Article A simple conductometric titration method is discussed for the determination of sulfhydryl groups in nonionic polymer networks, such as disulfide and alkylene sulfide crosslinked polycaprolactam fibers. The diffusion of the titrant into the crosslinked polymer is accomplished by swelling the network structure, thereby eliminating the necessity of destroying the crosslinks and/or breaking the polymer chains. [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1962 1962-04-01 /pmc/articles/PMC5315335/ http://dx.doi.org/10.6028/jres.066A.017 Text en https://creativecommons.org/publicdomain/zero/1.0/ The Journal of Research of the National Bureau of Standards Section A is a publication of the U.S. Government. The papers are in the public domain and are not subject to copyright in the United States. Articles from J Res may contain photographs or illustrations copyrighted by other commercial organizations or individuals that may not be used without obtaining prior approval from the holder of the copyright.
spellingShingle Article
Bruck, Stephen D.
Bailey, Sylvia M.
Conductometric Determination of Sulfhydryl Groups in Swollen Polycaprolactam Fibers Having Disulfide and Alkylene Sulfide Crosslinks
title Conductometric Determination of Sulfhydryl Groups in Swollen Polycaprolactam Fibers Having Disulfide and Alkylene Sulfide Crosslinks
title_full Conductometric Determination of Sulfhydryl Groups in Swollen Polycaprolactam Fibers Having Disulfide and Alkylene Sulfide Crosslinks
title_fullStr Conductometric Determination of Sulfhydryl Groups in Swollen Polycaprolactam Fibers Having Disulfide and Alkylene Sulfide Crosslinks
title_full_unstemmed Conductometric Determination of Sulfhydryl Groups in Swollen Polycaprolactam Fibers Having Disulfide and Alkylene Sulfide Crosslinks
title_short Conductometric Determination of Sulfhydryl Groups in Swollen Polycaprolactam Fibers Having Disulfide and Alkylene Sulfide Crosslinks
title_sort conductometric determination of sulfhydryl groups in swollen polycaprolactam fibers having disulfide and alkylene sulfide crosslinks
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5315335/
http://dx.doi.org/10.6028/jres.066A.017
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AT baileysylviam conductometricdeterminationofsulfhydrylgroupsinswollenpolycaprolactamfibershavingdisulfideandalkylenesulfidecrosslinks

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