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Modulating supramolecular binding of carbon dioxide in a redox-active porous metal-organic framework
Hydrogen bonds dominate many chemical and biological processes, and chemical modification enables control and modulation of host–guest systems. Here we report a targeted modification of hydrogen bonding and its effect on guest binding in redox-active materials. MFM-300(V(III)) {[V(III)(2)(OH)(2)(L)]...
Autores principales: | Lu, Zhenzhong, Godfrey, Harry G. W., da Silva, Ivan, Cheng, Yongqiang, Savage, Mathew, Tuna, Floriana, McInnes, Eric J. L., Teat, Simon J., Gagnon, Kevin J., Frogley, Mark D., Manuel, Pascal, Rudić, Svemir, Ramirez-Cuesta, Anibal J., Easun, Timothy L., Yang, Sihai, Schröder, Martin |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5316804/ https://www.ncbi.nlm.nih.gov/pubmed/28194014 http://dx.doi.org/10.1038/ncomms14212 |
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