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Enantioselective, convergent synthesis of the ineleganolide core by a tandem annulation cascade

An enantioselective and diastereoselective approach toward the synthesis of the polycyclic norditerpenoid ineleganolide is disclosed. A palladium-catalyzed enantioselective allylic alkylation is employed to stereoselectively construct the requisite chiral tertiary ether and facilitate the synthesis...

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Detalles Bibliográficos
Autores principales:	Craig, II, Robert A., Roizen, Jennifer L., Smith, Russell C., Jones, Amanda C., Virgil, Scott C., Stoltz, Brian M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5321630/ https://www.ncbi.nlm.nih.gov/pubmed/28239443 http://dx.doi.org/10.1039/c6sc03347d

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