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Tritium-Labeled Compounds IX. Determination of Isotope Effects in Reactions Yielding Water-t from Nonvolatile Reactants. Oxidation of Aldoses-1-t With Iodine
A convenient method is presented for estimating isotope effects in reactions which yield water-t. The water-t is separated by freeze-drying, and k*/k is calculated from the extent of the reaction and the ratio of the radioactivity of the water-t to that of the initial reactant. Application of the me...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
[Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology
1963
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5322772/ https://www.ncbi.nlm.nih.gov/pubmed/31580600 http://dx.doi.org/10.6028/jres.067A.054 |