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Tritium-Labeled Compounds X. Isotope Effects in the Oxidation of Aldoses-1-t With Bromine
Tritium isotope effects have been used in bromine oxidation studies of aldoses to evaluate two reaction paths previously postulated by Isbell and Pigman, namely, direct oxidation and oxidation after anomerization. Because the former path involves a primary isotope effect (k*/k = 0.14, approximately)...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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[Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology
1964
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5323084/ https://www.ncbi.nlm.nih.gov/pubmed/31834698 http://dx.doi.org/10.6028/jres.068A.013 |