Re‐Determination of the Crystal Structure of MIL‐91(Al)

The structure of one of the first permanently porous metal phosphonates, MIL‐91(Al) was re‐determined using high resolution synchrotron powder X‐ray diffraction data. The new model is in a lower symmetry space group, with no disordered ligands in the structure, whilst remaining otherwise consistent...

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Detalles Bibliográficos
Autores principales: Hermer, Nele, Wharmby, Michael T., Stock, Norbert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Short Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5324569/
https://www.ncbi.nlm.nih.gov/pubmed/28286349
http://dx.doi.org/10.1002/zaac.201600358
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author Hermer, Nele
Wharmby, Michael T.
Stock, Norbert
author_facet Hermer, Nele
Wharmby, Michael T.
Stock, Norbert
author_sort Hermer, Nele
collection PubMed
description The structure of one of the first permanently porous metal phosphonates, MIL‐91(Al) was re‐determined using high resolution synchrotron powder X‐ray diffraction data. The new model is in a lower symmetry space group, with no disordered ligands in the structure, whilst remaining otherwise consistent with the reported compound. New milder synthetic conditions were also developed.
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spelling pubmed-53245692017-03-08 Re‐Determination of the Crystal Structure of MIL‐91(Al) Hermer, Nele Wharmby, Michael T. Stock, Norbert Z Anorg Allg Chem Short Communications The structure of one of the first permanently porous metal phosphonates, MIL‐91(Al) was re‐determined using high resolution synchrotron powder X‐ray diffraction data. The new model is in a lower symmetry space group, with no disordered ligands in the structure, whilst remaining otherwise consistent with the reported compound. New milder synthetic conditions were also developed. John Wiley and Sons Inc. 2016-12-16 2017-01 /pmc/articles/PMC5324569/ /pubmed/28286349 http://dx.doi.org/10.1002/zaac.201600358 Text en © 2017 The Authors. Published by Wiley‐VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution (http://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Short Communications
Hermer, Nele
Wharmby, Michael T.
Stock, Norbert
Re‐Determination of the Crystal Structure of MIL‐91(Al)
title Re‐Determination of the Crystal Structure of MIL‐91(Al)
title_full Re‐Determination of the Crystal Structure of MIL‐91(Al)
title_fullStr Re‐Determination of the Crystal Structure of MIL‐91(Al)
title_full_unstemmed Re‐Determination of the Crystal Structure of MIL‐91(Al)
title_short Re‐Determination of the Crystal Structure of MIL‐91(Al)
title_sort re‐determination of the crystal structure of mil‐91(al)
topic Short Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5324569/
https://www.ncbi.nlm.nih.gov/pubmed/28286349
http://dx.doi.org/10.1002/zaac.201600358
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AT wharmbymichaelt redeterminationofthecrystalstructureofmil91al
AT stocknorbert redeterminationofthecrystalstructureofmil91al

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