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Rhodium‐Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids

Transformation of aromatic thioesters into arylboronic esters was achieved efficiently using a rhodium catalyst. The broad functional‐group tolerance and mild conditions of the method have allowed for the two‐step decarboxylative borylation of a wide range of aromatic carboxylic acids, including com...

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Detalles Bibliográficos
Autores principales: Ochiai, Hidenori, Uetake, Yuta, Niwa, Takashi, Hosoya, Takamitsu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5324605/
https://www.ncbi.nlm.nih.gov/pubmed/28124826
http://dx.doi.org/10.1002/anie.201611974
Descripción
Sumario:Transformation of aromatic thioesters into arylboronic esters was achieved efficiently using a rhodium catalyst. The broad functional‐group tolerance and mild conditions of the method have allowed for the two‐step decarboxylative borylation of a wide range of aromatic carboxylic acids, including commercially available drugs.