Rhodium‐Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids

Transformation of aromatic thioesters into arylboronic esters was achieved efficiently using a rhodium catalyst. The broad functional‐group tolerance and mild conditions of the method have allowed for the two‐step decarboxylative borylation of a wide range of aromatic carboxylic acids, including com...

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Autores principales: Ochiai, Hidenori, Uetake, Yuta, Niwa, Takashi, Hosoya, Takamitsu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5324605/
https://www.ncbi.nlm.nih.gov/pubmed/28124826
http://dx.doi.org/10.1002/anie.201611974
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author Ochiai, Hidenori
Uetake, Yuta
Niwa, Takashi
Hosoya, Takamitsu
author_facet Ochiai, Hidenori
Uetake, Yuta
Niwa, Takashi
Hosoya, Takamitsu
author_sort Ochiai, Hidenori
collection PubMed
description Transformation of aromatic thioesters into arylboronic esters was achieved efficiently using a rhodium catalyst. The broad functional‐group tolerance and mild conditions of the method have allowed for the two‐step decarboxylative borylation of a wide range of aromatic carboxylic acids, including commercially available drugs.
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spelling pubmed-53246052017-03-08 Rhodium‐Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids Ochiai, Hidenori Uetake, Yuta Niwa, Takashi Hosoya, Takamitsu Angew Chem Int Ed Engl Communications Transformation of aromatic thioesters into arylboronic esters was achieved efficiently using a rhodium catalyst. The broad functional‐group tolerance and mild conditions of the method have allowed for the two‐step decarboxylative borylation of a wide range of aromatic carboxylic acids, including commercially available drugs. John Wiley and Sons Inc. 2017-01-26 2017-02-20 /pmc/articles/PMC5324605/ /pubmed/28124826 http://dx.doi.org/10.1002/anie.201611974 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial (http://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Ochiai, Hidenori
Uetake, Yuta
Niwa, Takashi
Hosoya, Takamitsu
Rhodium‐Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids
title Rhodium‐Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids
title_full Rhodium‐Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids
title_fullStr Rhodium‐Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids
title_full_unstemmed Rhodium‐Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids
title_short Rhodium‐Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids
title_sort rhodium‐catalyzed decarbonylative borylation of aromatic thioesters for facile diversification of aromatic carboxylic acids
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5324605/
https://www.ncbi.nlm.nih.gov/pubmed/28124826
http://dx.doi.org/10.1002/anie.201611974
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AT niwatakashi rhodiumcatalyzeddecarbonylativeborylationofaromaticthioestersforfacilediversificationofaromaticcarboxylicacids
AT hosoyatakamitsu rhodiumcatalyzeddecarbonylativeborylationofaromaticthioestersforfacilediversificationofaromaticcarboxylicacids

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