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The 0–2 Transition of CO in Condensed Oxygen, Nitrogen, and Argon
Infrared absorption spectra of CO in the region of the first overtone have been observed in dilute (approximately 1 to 10 parts in 1000) liquid solutions of oxygen, nitrogen, and argon, and clear crystalline nitrogen and argon matrices. The overtone band was found at 4249.0, 4252.4, and 4252.0 cm(−1...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
[Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology
1964
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5327696/ https://www.ncbi.nlm.nih.gov/pubmed/31834729 http://dx.doi.org/10.6028/jres.068A.032 |
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author | Abramowitz, Stanley Broida, H. P. |
author_facet | Abramowitz, Stanley Broida, H. P. |
author_sort | Abramowitz, Stanley |
collection | PubMed |
description | Infrared absorption spectra of CO in the region of the first overtone have been observed in dilute (approximately 1 to 10 parts in 1000) liquid solutions of oxygen, nitrogen, and argon, and clear crystalline nitrogen and argon matrices. The overtone band was found at 4249.0, 4252.4, and 4252.0 cm(−1) with half widths of 18.4, 17.8, and 13.7 cm(−1) in liquid oxygen, nitrogen, and argon solutions at 82, 78, and 82 °K, respectively. The half width in liquid oxygen varied from 18.4 to 10.0 cm(−1) in the temperature range 82 to 57 °K. The band position was the same but its width was smaller in the crystalline nitrogen matrix. Two bands were observed in the clear crystalline argon solid at 4245 and 4256 cm(−1). The solution results cannot be interpreted with the recent theory of Buckingham. |
format | Online Article Text |
id | pubmed-5327696 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 1964 |
publisher | [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology |
record_format | MEDLINE/PubMed |
spelling | pubmed-53276962019-12-10 The 0–2 Transition of CO in Condensed Oxygen, Nitrogen, and Argon Abramowitz, Stanley Broida, H. P. J Res Natl Bur Stand A Phys Chem Article Infrared absorption spectra of CO in the region of the first overtone have been observed in dilute (approximately 1 to 10 parts in 1000) liquid solutions of oxygen, nitrogen, and argon, and clear crystalline nitrogen and argon matrices. The overtone band was found at 4249.0, 4252.4, and 4252.0 cm(−1) with half widths of 18.4, 17.8, and 13.7 cm(−1) in liquid oxygen, nitrogen, and argon solutions at 82, 78, and 82 °K, respectively. The half width in liquid oxygen varied from 18.4 to 10.0 cm(−1) in the temperature range 82 to 57 °K. The band position was the same but its width was smaller in the crystalline nitrogen matrix. Two bands were observed in the clear crystalline argon solid at 4245 and 4256 cm(−1). The solution results cannot be interpreted with the recent theory of Buckingham. [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1964 1964-06-01 /pmc/articles/PMC5327696/ /pubmed/31834729 http://dx.doi.org/10.6028/jres.068A.032 Text en https://creativecommons.org/publicdomain/zero/1.0/ The Journal of Research of the National Bureau of Standards Section A is a publication of the U.S. Government. The papers are in the public domain and are not subject to copyright in the United States. Articles from J Res may contain photographs or illustrations copyrighted by other commercial organizations or individuals that may not be used without obtaining prior approval from the holder of the copyright. |
spellingShingle | Article Abramowitz, Stanley Broida, H. P. The 0–2 Transition of CO in Condensed Oxygen, Nitrogen, and Argon |
title | The 0–2 Transition of CO in Condensed Oxygen, Nitrogen, and Argon |
title_full | The 0–2 Transition of CO in Condensed Oxygen, Nitrogen, and Argon |
title_fullStr | The 0–2 Transition of CO in Condensed Oxygen, Nitrogen, and Argon |
title_full_unstemmed | The 0–2 Transition of CO in Condensed Oxygen, Nitrogen, and Argon |
title_short | The 0–2 Transition of CO in Condensed Oxygen, Nitrogen, and Argon |
title_sort | 0–2 transition of co in condensed oxygen, nitrogen, and argon |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5327696/ https://www.ncbi.nlm.nih.gov/pubmed/31834729 http://dx.doi.org/10.6028/jres.068A.032 |
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