Cargando…

Stabilization of Two Radicals with One Metal: A Stepwise Coupling Model for Copper-Catalyzed Radical–Radical Cross-Coupling

Transition metal-catalyzed radical–radical cross-coupling reactions provide innovative methods for C–C and C–heteroatom bond construction. A theoretical study was performed to reveal the mechanism and selectivity of the copper-catalyzed C–N radical–radical cross-coupling reaction. The concerted coup...

Descripción completa

Detalles Bibliográficos
Autores principales:	Qi, Xiaotian, Zhu, Lei, Bai, Ruopeng, Lan, Yu
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group 2017
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5341085/ https://www.ncbi.nlm.nih.gov/pubmed/28272407 http://dx.doi.org/10.1038/srep43579

Ejemplares similares

Tuning the Reactivity of Radical through a Triplet Diradical Cu(II) Intermediate in Radical Oxidative Cross-Coupling
por: Zhou, Liangliang, et al.
Publicado: (2015)

Palladium catalyzed radical relay for the oxidative cross-coupling of quinolines
por: Zhao, Xiaorui, et al.
Publicado: (2022)

Pyridylphosphonium salts as alternatives to cyanopyridines in radical–radical coupling reactions
por: Greenwood, Jacob W., et al.
Publicado: (2021)

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings
por: Gutierrez, Osvaldo, et al.
Publicado: (2015)

Enantioselective catalytic β-amination through proton-coupled electron transfer followed by stereocontrolled radical–radical coupling
por: Zhou, Zijun, et al.
Publicado: (2017)

Carbene Radicals in Transition-Metal-Catalyzed Reactions
por: Epping, Roel F.J., et al.
Publicado: (2023)

Copper-catalyzed carbo-difluoromethylation of alkenes via radical relay
por: Cai, Aijie, et al.
Publicado: (2021)

Sensing array of radically coupled genetic biopixels
por: Prindle, Arthur, et al.
Publicado: (2011)

Carbene and photocatalyst-catalyzed decarboxylative radical coupling of carboxylic acids and acyl imidazoles to form ketones
por: Ren, Shi-Chao, et al.
Publicado: (2022)

Copper-catalyzed oxidative benzylic C-H cyclization via iminyl radical from intermolecular anion-radical redox relay
por: Shan, Xiang-Huan, et al.
Publicado: (2019)

Divergent Synthesis of Pyrone Diterpenes via Radical Cross Coupling
por: Merchant, Rohan R., et al.
Publicado: (2018)

Reductive Cross-Coupling of Olefins via a Radical Pathway
por: Zhou, Wei, et al.
Publicado: (2023)

A visible-light activated secondary phosphine oxide ligand enabling Pd-catalyzed radical cross-couplings
por: Kuribara, Takahito, et al.
Publicado: (2022)

Recent developments in copper-catalyzed radical alkylations of electron-rich π-systems
por: Shimkin, Kirk W, et al.
Publicado: (2015)

Copper-catalyzed aerobic oxidative radical alkoxycyclization of tryptamines to access 3-alkoxypyrroloindolines
por: Wang, Wei, et al.
Publicado: (2021)

Metal-free, intermolecular carbopyridylation of alkenes via visible-light-induced reductive radical coupling
por: Chen, Dan, et al.
Publicado: (2018)

Tuning the separation and coupling of corannulene trianion-radicals through sizable alkali metal belts
por: Spisak, Sarah N., et al.
Publicado: (2017)

α‐Amino Radical Halogen Atom Transfer Agents for Metallaphotoredox‐Catalyzed Cross‐Electrophile Couplings of Distinct Organic Halides
por: Tian, Xianhai, et al.
Publicado: (2022)

Synthesis of aryl sulfides via radical–radical cross coupling of electron-rich arenes using visible light photoredox catalysis
por: Das, Amrita, et al.
Publicado: (2018)

Copper-catalysed benzylic C–H coupling with alcohols via radical relay enabled by redox buffering
por: Hu, Huayou, et al.
Publicado: (2020)

Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes
por: Zhu, Rong, et al.
Publicado: (2015)

Copper-catalyzed aerobic radical C–C bond cleavage of N–H ketimines
por: Tnay, Ya Lin, et al.
Publicado: (2015)

Copper‐Catalyzed Double Additions and Radical Cyclization Cascades in the Re‐Engineering of the Antibacterial Pleuromutilin
por: Ruscoe, Rebecca E., et al.
Publicado: (2015)

Copper-catalyzed radical trans-selective hydroboration of ynamides with N-heterocyclic carbene boranes
por: Wang, Kefeng, et al.
Publicado: (2022)

Investigating the Mechanism of Ni-Catalyzed Coupling of Photoredox-Generated Alkyl Radicals and Aryl Bromides: A Computational Study
por: Sanosa, Nil, et al.
Publicado: (2023)

Stepwise radical cation Diels–Alder reaction via multiple pathways
por: Shimizu, Ryo, et al.
Publicado: (2018)

Copper-catalyzed aerobic oxidative coupling: From ketone and diamine to pyrazine
por: Wu, Kun, et al.
Publicado: (2015)

Bismuth radical catalysis in the activation and coupling of redox-active electrophiles
por: Mato, Mauro, et al.
Publicado: (2023)

An Air‐Stable, Neutral Phenothiazinyl Radical with Substantial Radical Stabilization Energy
por: Sigmund, Lukas M., et al.
Publicado: (2020)

Insight into Radical Initiation, Solvent Effects, and Biphenyl Production in Iron–Bisphosphine Cross-Couplings
por: Aguilera, Maria Camila, et al.
Publicado: (2023)

Synthesis of triarylmethanes by silyl radical-mediated cross-coupling of aryl fluorides and arylmethanes
por: Zhou, Jun, et al.
Publicado: (2023)

Alcohol imination catalyzed by carbon nanostructures synthesized by C(sp(2))-C(sp(3)) free radical coupling
por: Wang, Cheng, et al.
Publicado: (2023)

Gauging Radical Stabilization with Carbenes
por: Breitwieser, Kevin, et al.
Publicado: (2022)

Cobalt-catalyzed radical-mediated carbon–carbon scission via a radical-type migratory insertion
por: Liu, Jian-Biao, et al.
Publicado: (2023)

Copper-catalyzed radical cascade reaction of simple cyclobutanes: synthesis of highly functionalized cyclobutene derivatives
por: Liu, Chunyang, et al.
Publicado: (2022)

Visible Light Photoredox-Catalyzed Decarboxylative Alkylation of 3-Aryl-Oxetanes and Azetidines via Benzylic Tertiary Radicals and Implications of Benzylic Radical Stability
por: Dubois, Maryne A. J., et al.
Publicado: (2023)

Hydrodynamic cavitation coupled with zero-valent iron produces radical sulfate radicals by sulfite activation to degrade direct red 83
por: Azizollahi, Nastaran, et al.
Publicado: (2023)

Stable 2D anti-ferromagnetically coupled fluorenyl radical dendrons
por: Wang, Jian, et al.
Publicado: (2018)

Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer
por: Abbenseth, Josh, et al.
Publicado: (2019)

Catalytic enantioselective radical coupling of activated ketones with N-aryl glycines
por: Liu, Yang, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_0vic68ok0mvgg1jcft77ind62r