Cargando…
Stabilization of Two Radicals with One Metal: A Stepwise Coupling Model for Copper-Catalyzed Radical–Radical Cross-Coupling
Transition metal-catalyzed radical–radical cross-coupling reactions provide innovative methods for C–C and C–heteroatom bond construction. A theoretical study was performed to reveal the mechanism and selectivity of the copper-catalyzed C–N radical–radical cross-coupling reaction. The concerted coup...
Autores principales: | Qi, Xiaotian, Zhu, Lei, Bai, Ruopeng, Lan, Yu |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2017
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5341085/ https://www.ncbi.nlm.nih.gov/pubmed/28272407 http://dx.doi.org/10.1038/srep43579 |
Ejemplares similares
-
Tuning the Reactivity of Radical through a Triplet Diradical Cu(II) Intermediate in Radical Oxidative Cross-Coupling
por: Zhou, Liangliang, et al.
Publicado: (2015) -
Palladium catalyzed radical relay for the oxidative cross-coupling of quinolines
por: Zhao, Xiaorui, et al.
Publicado: (2022) -
Pyridylphosphonium salts as alternatives to cyanopyridines in radical–radical coupling reactions
por: Greenwood, Jacob W., et al.
Publicado: (2021) -
Nickel-Catalyzed
Cross-Coupling of Photoredox-Generated
Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed
Cross-Couplings
por: Gutierrez, Osvaldo, et al.
Publicado: (2015) -
Enantioselective catalytic β-amination through proton-coupled electron transfer followed by stereocontrolled radical–radical coupling
por: Zhou, Zijun, et al.
Publicado: (2017)