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Crystal structure of a Co(II) coordination polymer: catena-poly[[μ-aqua-bis(μ-2-methylpropanoato)-κ(2) O:O′;κ(2) O:O-cobalt(II)] monohydrate]
In the title cobalt(II) coordination polymer with isobutyrate ligands, {[Co{CH(CH(3))(2)CO(2)}(2)(H(2)O)]·H(2)O}(n), the Co(2+) ion is hexacoordinated in a slightly distorted octahedral coordination environment defined by two O atoms from two bridging water molecules and four O atoms from four br...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347044/ https://www.ncbi.nlm.nih.gov/pubmed/28316799 http://dx.doi.org/10.1107/S2056989017001360 |
| _version_ | 1782513995059560448 |
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| author | Fischer, Andrei I. Gurzhiy, Vladislav V. Aleksandrova, Julia V. Pakina, Maria I. |
| author_facet | Fischer, Andrei I. Gurzhiy, Vladislav V. Aleksandrova, Julia V. Pakina, Maria I. |
| author_sort | Fischer, Andrei I. |
| collection | PubMed |
| description | In the title cobalt(II) coordination polymer with isobutyrate ligands, {[Co{CH(CH(3))(2)CO(2)}(2)(H(2)O)]·H(2)O}(n), the Co(2+) ion is hexacoordinated in a slightly distorted octahedral coordination environment defined by two O atoms from two bridging water molecules and four O atoms from four bridging carboxylate ligands. The carboxylates adopt two different coordination modes, μ-(κ(2) O:O′) and μ-(κ(2) O:O), forming a one-dimensional polymeric chain extending along [010]. The intra-chain cobalt⋯cobalt separation is 3.2029 (2) Å. The polymeric chains are linked by hydrogen bonds involving the water molecules of solvation, giving a two-dimensional network structure lying parallel to (100). |
| format | Online Article Text |
| id | pubmed-5347044 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2017 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-53470442017-03-17 Crystal structure of a Co(II) coordination polymer: catena-poly[[μ-aqua-bis(μ-2-methylpropanoato)-κ(2) O:O′;κ(2) O:O-cobalt(II)] monohydrate] Fischer, Andrei I. Gurzhiy, Vladislav V. Aleksandrova, Julia V. Pakina, Maria I. Acta Crystallogr E Crystallogr Commun Research Communications In the title cobalt(II) coordination polymer with isobutyrate ligands, {[Co{CH(CH(3))(2)CO(2)}(2)(H(2)O)]·H(2)O}(n), the Co(2+) ion is hexacoordinated in a slightly distorted octahedral coordination environment defined by two O atoms from two bridging water molecules and four O atoms from four bridging carboxylate ligands. The carboxylates adopt two different coordination modes, μ-(κ(2) O:O′) and μ-(κ(2) O:O), forming a one-dimensional polymeric chain extending along [010]. The intra-chain cobalt⋯cobalt separation is 3.2029 (2) Å. The polymeric chains are linked by hydrogen bonds involving the water molecules of solvation, giving a two-dimensional network structure lying parallel to (100). International Union of Crystallography 2017-02-03 /pmc/articles/PMC5347044/ /pubmed/28316799 http://dx.doi.org/10.1107/S2056989017001360 Text en © Fischer et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| spellingShingle | Research Communications Fischer, Andrei I. Gurzhiy, Vladislav V. Aleksandrova, Julia V. Pakina, Maria I. Crystal structure of a Co(II) coordination polymer: catena-poly[[μ-aqua-bis(μ-2-methylpropanoato)-κ(2) O:O′;κ(2) O:O-cobalt(II)] monohydrate] |
| title | Crystal structure of a Co(II) coordination polymer: catena-poly[[μ-aqua-bis(μ-2-methylpropanoato)-κ(2)
O:O′;κ(2)
O:O-cobalt(II)] monohydrate] |
| title_full | Crystal structure of a Co(II) coordination polymer: catena-poly[[μ-aqua-bis(μ-2-methylpropanoato)-κ(2)
O:O′;κ(2)
O:O-cobalt(II)] monohydrate] |
| title_fullStr | Crystal structure of a Co(II) coordination polymer: catena-poly[[μ-aqua-bis(μ-2-methylpropanoato)-κ(2)
O:O′;κ(2)
O:O-cobalt(II)] monohydrate] |
| title_full_unstemmed | Crystal structure of a Co(II) coordination polymer: catena-poly[[μ-aqua-bis(μ-2-methylpropanoato)-κ(2)
O:O′;κ(2)
O:O-cobalt(II)] monohydrate] |
| title_short | Crystal structure of a Co(II) coordination polymer: catena-poly[[μ-aqua-bis(μ-2-methylpropanoato)-κ(2)
O:O′;κ(2)
O:O-cobalt(II)] monohydrate] |
| title_sort | crystal structure of a co(ii) coordination polymer: catena-poly[[μ-aqua-bis(μ-2-methylpropanoato)-κ(2)
o:o′;κ(2)
o:o-cobalt(ii)] monohydrate] |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347044/ https://www.ncbi.nlm.nih.gov/pubmed/28316799 http://dx.doi.org/10.1107/S2056989017001360 |
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