Synthesis and structure of the mercury chloride complex of 2,2′-(2-bromo-5-tert-butyl-1,3-phenyl­ene)bis­(1-methyl-1H-benzimidazole)

In the title mercury complex, catena-poly[[di­chlorido­mercury(II)]-μ-2,2′-(2-bromo-5-tert-butyl-1,3-phenyl­ene)bis­(1-methyl-1H-benzimidazole)-κ(2) N (3):N (3′)], [HgCl(2)(C(26)H(25)BrN(4))](n), the Hg(II) atom is coordinated by two Cl atoms and by two N atoms from two 2,2′-(2-bromo-5-tert-butyl-1,...

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Autores principales: Rani, Varsha, Singh, Harkesh B., Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347049/
https://www.ncbi.nlm.nih.gov/pubmed/28316804
http://dx.doi.org/10.1107/S2056989017001888
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author Rani, Varsha
Singh, Harkesh B.
Butcher, Ray J.
author_facet Rani, Varsha
Singh, Harkesh B.
Butcher, Ray J.
author_sort Rani, Varsha
collection PubMed
description In the title mercury complex, catena-poly[[di­chlorido­mercury(II)]-μ-2,2′-(2-bromo-5-tert-butyl-1,3-phenyl­ene)bis­(1-methyl-1H-benzimidazole)-κ(2) N (3):N (3′)], [HgCl(2)(C(26)H(25)BrN(4))](n), the Hg(II) atom is coordinated by two Cl atoms and by two N atoms from two 2,2′-(2-bromo-5-tert-butyl-1,3-phenyl­ene)bis­(1-methyl-1H-benzimidazole) ligands. The metal cation adopts a distorted tetrahedral coordination geometry with with bond angles around mercury of 100.59 (15)° [N—Hg—N] and 126.35 (7)° [Cl—Hg—Cl]. This arrangement gives rise to a zigzag helical 1-D polymer propagating along the b-axis direction.
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spelling pubmed-53470492017-03-17 Synthesis and structure of the mercury chloride complex of 2,2′-(2-bromo-5-tert-butyl-1,3-phenyl­ene)bis­(1-methyl-1H-benzimidazole) Rani, Varsha Singh, Harkesh B. Butcher, Ray J. Acta Crystallogr E Crystallogr Commun Research Communications In the title mercury complex, catena-poly[[di­chlorido­mercury(II)]-μ-2,2′-(2-bromo-5-tert-butyl-1,3-phenyl­ene)bis­(1-methyl-1H-benzimidazole)-κ(2) N (3):N (3′)], [HgCl(2)(C(26)H(25)BrN(4))](n), the Hg(II) atom is coordinated by two Cl atoms and by two N atoms from two 2,2′-(2-bromo-5-tert-butyl-1,3-phenyl­ene)bis­(1-methyl-1H-benzimidazole) ligands. The metal cation adopts a distorted tetrahedral coordination geometry with with bond angles around mercury of 100.59 (15)° [N—Hg—N] and 126.35 (7)° [Cl—Hg—Cl]. This arrangement gives rise to a zigzag helical 1-D polymer propagating along the b-axis direction. International Union of Crystallography 2017-02-10 /pmc/articles/PMC5347049/ /pubmed/28316804 http://dx.doi.org/10.1107/S2056989017001888 Text en © Rani et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Rani, Varsha
Singh, Harkesh B.
Butcher, Ray J.
Synthesis and structure of the mercury chloride complex of 2,2′-(2-bromo-5-tert-butyl-1,3-phenyl­ene)bis­(1-methyl-1H-benzimidazole)
title Synthesis and structure of the mercury chloride complex of 2,2′-(2-bromo-5-tert-butyl-1,3-phenyl­ene)bis­(1-methyl-1H-benzimidazole)
title_full Synthesis and structure of the mercury chloride complex of 2,2′-(2-bromo-5-tert-butyl-1,3-phenyl­ene)bis­(1-methyl-1H-benzimidazole)
title_fullStr Synthesis and structure of the mercury chloride complex of 2,2′-(2-bromo-5-tert-butyl-1,3-phenyl­ene)bis­(1-methyl-1H-benzimidazole)
title_full_unstemmed Synthesis and structure of the mercury chloride complex of 2,2′-(2-bromo-5-tert-butyl-1,3-phenyl­ene)bis­(1-methyl-1H-benzimidazole)
title_short Synthesis and structure of the mercury chloride complex of 2,2′-(2-bromo-5-tert-butyl-1,3-phenyl­ene)bis­(1-methyl-1H-benzimidazole)
title_sort synthesis and structure of the mercury chloride complex of 2,2′-(2-bromo-5-tert-butyl-1,3-phenyl­ene)bis­(1-methyl-1h-benzimidazole)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347049/
https://www.ncbi.nlm.nih.gov/pubmed/28316804
http://dx.doi.org/10.1107/S2056989017001888
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AT butcherrayj synthesisandstructureofthemercurychloridecomplexof222bromo5tertbutyl13phenylenebis1methyl1hbenzimidazole

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