Crystal structure of the monoclinic phase (phase IV) of bis­(tetra­methyl­ammonium) tetra­chlorido­cuprate(II)

The crystal structure of the low-temperature monoclinic phase of the title compound, [(CH(3))(4)N](2)[CuCl(4)], was determined at 120 K. The structure of the room-temperature phase has been determined in the ortho­rhom­bic space group Pmcm [Morosin & Lingafelter (1961 ▸). J. Phys. Chem. 50–51; C...

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Detalles Bibliográficos
Autores principales: Seck, Gorgui Awa, Diop, Libasse, Oliver, Allen G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347053/
https://www.ncbi.nlm.nih.gov/pubmed/28316808
http://dx.doi.org/10.1107/S2056989017002146
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author Seck, Gorgui Awa
Diop, Libasse
Oliver, Allen G.
author_facet Seck, Gorgui Awa
Diop, Libasse
Oliver, Allen G.
author_sort Seck, Gorgui Awa
collection PubMed
description The crystal structure of the low-temperature monoclinic phase of the title compound, [(CH(3))(4)N](2)[CuCl(4)], was determined at 120 K. The structure of the room-temperature phase has been determined in the ortho­rhom­bic space group Pmcm [Morosin & Lingafelter (1961 ▸). J. Phys. Chem. 50–51; Clay et al. (1975 ▸). Acta Cryst. B31 289–290]. The asymmetric unit consists of one discrete tetra­chlorido­cuprate anion with a distorted tetra­hedral geometry and two tetra­methyl­ammonium cations. In the crystal, the cations and the anions are linked via weak C—H⋯Cl hydrogen bonds.
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spelling pubmed-53470532017-03-17 Crystal structure of the monoclinic phase (phase IV) of bis­(tetra­methyl­ammonium) tetra­chlorido­cuprate(II) Seck, Gorgui Awa Diop, Libasse Oliver, Allen G. Acta Crystallogr E Crystallogr Commun Research Communications The crystal structure of the low-temperature monoclinic phase of the title compound, [(CH(3))(4)N](2)[CuCl(4)], was determined at 120 K. The structure of the room-temperature phase has been determined in the ortho­rhom­bic space group Pmcm [Morosin & Lingafelter (1961 ▸). J. Phys. Chem. 50–51; Clay et al. (1975 ▸). Acta Cryst. B31 289–290]. The asymmetric unit consists of one discrete tetra­chlorido­cuprate anion with a distorted tetra­hedral geometry and two tetra­methyl­ammonium cations. In the crystal, the cations and the anions are linked via weak C—H⋯Cl hydrogen bonds. International Union of Crystallography 2017-02-14 /pmc/articles/PMC5347053/ /pubmed/28316808 http://dx.doi.org/10.1107/S2056989017002146 Text en © Seck et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Seck, Gorgui Awa
Diop, Libasse
Oliver, Allen G.
Crystal structure of the monoclinic phase (phase IV) of bis­(tetra­methyl­ammonium) tetra­chlorido­cuprate(II)
title Crystal structure of the monoclinic phase (phase IV) of bis­(tetra­methyl­ammonium) tetra­chlorido­cuprate(II)
title_full Crystal structure of the monoclinic phase (phase IV) of bis­(tetra­methyl­ammonium) tetra­chlorido­cuprate(II)
title_fullStr Crystal structure of the monoclinic phase (phase IV) of bis­(tetra­methyl­ammonium) tetra­chlorido­cuprate(II)
title_full_unstemmed Crystal structure of the monoclinic phase (phase IV) of bis­(tetra­methyl­ammonium) tetra­chlorido­cuprate(II)
title_short Crystal structure of the monoclinic phase (phase IV) of bis­(tetra­methyl­ammonium) tetra­chlorido­cuprate(II)
title_sort crystal structure of the monoclinic phase (phase iv) of bis­(tetra­methyl­ammonium) tetra­chlorido­cuprate(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347053/
https://www.ncbi.nlm.nih.gov/pubmed/28316808
http://dx.doi.org/10.1107/S2056989017002146
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AT dioplibasse crystalstructureofthemonoclinicphasephaseivofbistetramethylammoniumtetrachloridocuprateii
AT oliveralleng crystalstructureofthemonoclinicphasephaseivofbistetramethylammoniumtetrachloridocuprateii

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