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Crystal structure of bis­(aceto­nitrile-κN)bis­(4-benzoyl­pyridine-κN)bis­(thio­cyanato-κN)cobalt(II)

The crystal structure of the title compound, [Co(NCS)(2)(C(2)H(3)N)(2)(C(12)H(9)NO)(2)], consists of cobalt(II) cations that are octa­hedrally coordinated by the N atoms of two terminal thio­cyanate anions, two aceto­nitrile mol­ecules and two 4-benzoyl­pyridine ligands. The discrete complexes are l...

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Detalles Bibliográficos
Autores principales: Suckert, Stefan, Werner, Julia, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347055/
https://www.ncbi.nlm.nih.gov/pubmed/28316810
http://dx.doi.org/10.1107/S2056989017002201
Descripción
Sumario:The crystal structure of the title compound, [Co(NCS)(2)(C(2)H(3)N)(2)(C(12)H(9)NO)(2)], consists of cobalt(II) cations that are octa­hedrally coordinated by the N atoms of two terminal thio­cyanate anions, two aceto­nitrile mol­ecules and two 4-benzoyl­pyridine ligands. The discrete complexes are located on centres of inversion. They are connected by weak inter­molecular C—H⋯O and C—H⋯S hydrogen-bonding inter­actions between one of the pyridine H atoms and the carbonyl O atom, and between one of the methyl H atoms of the aceto­nitrile mol­ecule and the thio­cyanate S atoms into layers parallel to (101). No pronounced inter­molecular inter­actions are observed between these layers.