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Crystal structure of bis­(aceto­nitrile-κN)bis­(4-benzoyl­pyridine-κN)bis­(thio­cyanato-κN)cobalt(II)

The crystal structure of the title compound, [Co(NCS)(2)(C(2)H(3)N)(2)(C(12)H(9)NO)(2)], consists of cobalt(II) cations that are octa­hedrally coordinated by the N atoms of two terminal thio­cyanate anions, two aceto­nitrile mol­ecules and two 4-benzoyl­pyridine ligands. The discrete complexes are l...

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Detalles Bibliográficos
Autores principales: Suckert, Stefan, Werner, Julia, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347055/
https://www.ncbi.nlm.nih.gov/pubmed/28316810
http://dx.doi.org/10.1107/S2056989017002201
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author Suckert, Stefan
Werner, Julia
Jess, Inke
Näther, Christian
author_facet Suckert, Stefan
Werner, Julia
Jess, Inke
Näther, Christian
author_sort Suckert, Stefan
collection PubMed
description The crystal structure of the title compound, [Co(NCS)(2)(C(2)H(3)N)(2)(C(12)H(9)NO)(2)], consists of cobalt(II) cations that are octa­hedrally coordinated by the N atoms of two terminal thio­cyanate anions, two aceto­nitrile mol­ecules and two 4-benzoyl­pyridine ligands. The discrete complexes are located on centres of inversion. They are connected by weak inter­molecular C—H⋯O and C—H⋯S hydrogen-bonding inter­actions between one of the pyridine H atoms and the carbonyl O atom, and between one of the methyl H atoms of the aceto­nitrile mol­ecule and the thio­cyanate S atoms into layers parallel to (101). No pronounced inter­molecular inter­actions are observed between these layers.
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spelling pubmed-53470552017-03-17 Crystal structure of bis­(aceto­nitrile-κN)bis­(4-benzoyl­pyridine-κN)bis­(thio­cyanato-κN)cobalt(II) Suckert, Stefan Werner, Julia Jess, Inke Näther, Christian Acta Crystallogr E Crystallogr Commun Research Communications The crystal structure of the title compound, [Co(NCS)(2)(C(2)H(3)N)(2)(C(12)H(9)NO)(2)], consists of cobalt(II) cations that are octa­hedrally coordinated by the N atoms of two terminal thio­cyanate anions, two aceto­nitrile mol­ecules and two 4-benzoyl­pyridine ligands. The discrete complexes are located on centres of inversion. They are connected by weak inter­molecular C—H⋯O and C—H⋯S hydrogen-bonding inter­actions between one of the pyridine H atoms and the carbonyl O atom, and between one of the methyl H atoms of the aceto­nitrile mol­ecule and the thio­cyanate S atoms into layers parallel to (101). No pronounced inter­molecular inter­actions are observed between these layers. International Union of Crystallography 2017-02-14 /pmc/articles/PMC5347055/ /pubmed/28316810 http://dx.doi.org/10.1107/S2056989017002201 Text en © Suckert et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Suckert, Stefan
Werner, Julia
Jess, Inke
Näther, Christian
Crystal structure of bis­(aceto­nitrile-κN)bis­(4-benzoyl­pyridine-κN)bis­(thio­cyanato-κN)cobalt(II)
title Crystal structure of bis­(aceto­nitrile-κN)bis­(4-benzoyl­pyridine-κN)bis­(thio­cyanato-κN)cobalt(II)
title_full Crystal structure of bis­(aceto­nitrile-κN)bis­(4-benzoyl­pyridine-κN)bis­(thio­cyanato-κN)cobalt(II)
title_fullStr Crystal structure of bis­(aceto­nitrile-κN)bis­(4-benzoyl­pyridine-κN)bis­(thio­cyanato-κN)cobalt(II)
title_full_unstemmed Crystal structure of bis­(aceto­nitrile-κN)bis­(4-benzoyl­pyridine-κN)bis­(thio­cyanato-κN)cobalt(II)
title_short Crystal structure of bis­(aceto­nitrile-κN)bis­(4-benzoyl­pyridine-κN)bis­(thio­cyanato-κN)cobalt(II)
title_sort crystal structure of bis­(aceto­nitrile-κn)bis­(4-benzoyl­pyridine-κn)bis­(thio­cyanato-κn)cobalt(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347055/
https://www.ncbi.nlm.nih.gov/pubmed/28316810
http://dx.doi.org/10.1107/S2056989017002201
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