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Crystal structure of bis(acetonitrile-κN)bis(4-benzoylpyridine-κN)bis(thiocyanato-κN)cobalt(II)
The crystal structure of the title compound, [Co(NCS)(2)(C(2)H(3)N)(2)(C(12)H(9)NO)(2)], consists of cobalt(II) cations that are octahedrally coordinated by the N atoms of two terminal thiocyanate anions, two acetonitrile molecules and two 4-benzoylpyridine ligands. The discrete complexes are l...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347055/ https://www.ncbi.nlm.nih.gov/pubmed/28316810 http://dx.doi.org/10.1107/S2056989017002201 |
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author | Suckert, Stefan Werner, Julia Jess, Inke Näther, Christian |
author_facet | Suckert, Stefan Werner, Julia Jess, Inke Näther, Christian |
author_sort | Suckert, Stefan |
collection | PubMed |
description | The crystal structure of the title compound, [Co(NCS)(2)(C(2)H(3)N)(2)(C(12)H(9)NO)(2)], consists of cobalt(II) cations that are octahedrally coordinated by the N atoms of two terminal thiocyanate anions, two acetonitrile molecules and two 4-benzoylpyridine ligands. The discrete complexes are located on centres of inversion. They are connected by weak intermolecular C—H⋯O and C—H⋯S hydrogen-bonding interactions between one of the pyridine H atoms and the carbonyl O atom, and between one of the methyl H atoms of the acetonitrile molecule and the thiocyanate S atoms into layers parallel to (101). No pronounced intermolecular interactions are observed between these layers. |
format | Online Article Text |
id | pubmed-5347055 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-53470552017-03-17 Crystal structure of bis(acetonitrile-κN)bis(4-benzoylpyridine-κN)bis(thiocyanato-κN)cobalt(II) Suckert, Stefan Werner, Julia Jess, Inke Näther, Christian Acta Crystallogr E Crystallogr Commun Research Communications The crystal structure of the title compound, [Co(NCS)(2)(C(2)H(3)N)(2)(C(12)H(9)NO)(2)], consists of cobalt(II) cations that are octahedrally coordinated by the N atoms of two terminal thiocyanate anions, two acetonitrile molecules and two 4-benzoylpyridine ligands. The discrete complexes are located on centres of inversion. They are connected by weak intermolecular C—H⋯O and C—H⋯S hydrogen-bonding interactions between one of the pyridine H atoms and the carbonyl O atom, and between one of the methyl H atoms of the acetonitrile molecule and the thiocyanate S atoms into layers parallel to (101). No pronounced intermolecular interactions are observed between these layers. International Union of Crystallography 2017-02-14 /pmc/articles/PMC5347055/ /pubmed/28316810 http://dx.doi.org/10.1107/S2056989017002201 Text en © Suckert et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Suckert, Stefan Werner, Julia Jess, Inke Näther, Christian Crystal structure of bis(acetonitrile-κN)bis(4-benzoylpyridine-κN)bis(thiocyanato-κN)cobalt(II) |
title | Crystal structure of bis(acetonitrile-κN)bis(4-benzoylpyridine-κN)bis(thiocyanato-κN)cobalt(II) |
title_full | Crystal structure of bis(acetonitrile-κN)bis(4-benzoylpyridine-κN)bis(thiocyanato-κN)cobalt(II) |
title_fullStr | Crystal structure of bis(acetonitrile-κN)bis(4-benzoylpyridine-κN)bis(thiocyanato-κN)cobalt(II) |
title_full_unstemmed | Crystal structure of bis(acetonitrile-κN)bis(4-benzoylpyridine-κN)bis(thiocyanato-κN)cobalt(II) |
title_short | Crystal structure of bis(acetonitrile-κN)bis(4-benzoylpyridine-κN)bis(thiocyanato-κN)cobalt(II) |
title_sort | crystal structure of bis(acetonitrile-κn)bis(4-benzoylpyridine-κn)bis(thiocyanato-κn)cobalt(ii) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347055/ https://www.ncbi.nlm.nih.gov/pubmed/28316810 http://dx.doi.org/10.1107/S2056989017002201 |
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