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[N′-(4-Decyloxy-2-oxidobenzylidene)-3-hydroxy-2-naphthohydrazidato-κ(3) N,O,O′]dimethyltin(IV): crystal structure and Hirshfeld surface analysis
The title diorganotin compound, [Sn(CH(3))(2)(C(28)H(32)N(2)O(4))], features a distorted SnC(2)NO(2) coordination geometry almost intermediate between ideal trigonal–bipyramidal and square-pyramidal. The dianionic Schiff base ligand coordinates in a tridentate fashion via two alkoxide O and hydrazi...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347062/ https://www.ncbi.nlm.nih.gov/pubmed/28316817 http://dx.doi.org/10.1107/S2056989017002365 |
Sumario: | The title diorganotin compound, [Sn(CH(3))(2)(C(28)H(32)N(2)O(4))], features a distorted SnC(2)NO(2) coordination geometry almost intermediate between ideal trigonal–bipyramidal and square-pyramidal. The dianionic Schiff base ligand coordinates in a tridentate fashion via two alkoxide O and hydrazinyl N atoms; an intramolecular hydroxy-O—H⋯N(hydrazinyl) hydrogen bond is noted. The alkoxy chain has an all-trans conformation, and to the first approximation, the molecule has local mirror symmetry relating the two Sn-bound methyl groups. Supramolecular layers sustained by imine-C—H⋯O(hydroxy), π–π [between decyloxy-substituted benzene rings with an inter-centroid separation of 3.7724 (13) Å], C—H⋯π(arene) and C—H⋯π(chelate ring) interactions are formed in the crystal; layers stack along the c axis with no directional interactions between them. The presence of C—H⋯π(chelate ring) interactions in the crystal is clearly evident from an analysis of the calculated Hirshfeld surface. |
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