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[N′-(4-Dec­yloxy-2-oxido­benzyl­idene)-3-hy­droxy-2-naphtho­hydrazidato-κ(3) N,O,O′]di­methyl­tin(IV): crystal structure and Hirshfeld surface analysis

The title diorganotin compound, [Sn(CH(3))(2)(C(28)H(32)N(2)O(4))], features a distorted SnC(2)NO(2) coordination geometry almost inter­mediate between ideal trigonal–bipyramidal and square-pyramidal. The dianionic Schiff base ligand coordinates in a tridentate fashion via two alkoxide O and hydrazi...

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Autores principales: Rosely, Siti Nadiah Binti Mohd, Hussen, Rusnah Syahila Duali, Lee, See Mun, Halcovitch, Nathan R., Jotani, Mukesh M., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347062/
https://www.ncbi.nlm.nih.gov/pubmed/28316817
http://dx.doi.org/10.1107/S2056989017002365
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author Rosely, Siti Nadiah Binti Mohd
Hussen, Rusnah Syahila Duali
Lee, See Mun
Halcovitch, Nathan R.
Jotani, Mukesh M.
Tiekink, Edward R. T.
author_facet Rosely, Siti Nadiah Binti Mohd
Hussen, Rusnah Syahila Duali
Lee, See Mun
Halcovitch, Nathan R.
Jotani, Mukesh M.
Tiekink, Edward R. T.
author_sort Rosely, Siti Nadiah Binti Mohd
collection PubMed
description The title diorganotin compound, [Sn(CH(3))(2)(C(28)H(32)N(2)O(4))], features a distorted SnC(2)NO(2) coordination geometry almost inter­mediate between ideal trigonal–bipyramidal and square-pyramidal. The dianionic Schiff base ligand coordinates in a tridentate fashion via two alkoxide O and hydrazinyl N atoms; an intra­molecular hy­droxy-O—H⋯N(hydrazin­yl) hydrogen bond is noted. The alk­oxy chain has an all-trans conformation, and to the first approximation, the mol­ecule has local mirror symmetry relating the two Sn-bound methyl groups. Supra­molecular layers sustained by imine-C—H⋯O(hy­droxy), π–π [between dec­yloxy-substituted benzene rings with an inter-centroid separation of 3.7724 (13) Å], C—H⋯π(arene) and C—H⋯π(chelate ring) inter­actions are formed in the crystal; layers stack along the c axis with no directional inter­actions between them. The presence of C—H⋯π(chelate ring) inter­actions in the crystal is clearly evident from an analysis of the calculated Hirshfeld surface.
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spelling pubmed-53470622017-03-17 [N′-(4-Dec­yloxy-2-oxido­benzyl­idene)-3-hy­droxy-2-naphtho­hydrazidato-κ(3) N,O,O′]di­methyl­tin(IV): crystal structure and Hirshfeld surface analysis Rosely, Siti Nadiah Binti Mohd Hussen, Rusnah Syahila Duali Lee, See Mun Halcovitch, Nathan R. Jotani, Mukesh M. Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Research Communications The title diorganotin compound, [Sn(CH(3))(2)(C(28)H(32)N(2)O(4))], features a distorted SnC(2)NO(2) coordination geometry almost inter­mediate between ideal trigonal–bipyramidal and square-pyramidal. The dianionic Schiff base ligand coordinates in a tridentate fashion via two alkoxide O and hydrazinyl N atoms; an intra­molecular hy­droxy-O—H⋯N(hydrazin­yl) hydrogen bond is noted. The alk­oxy chain has an all-trans conformation, and to the first approximation, the mol­ecule has local mirror symmetry relating the two Sn-bound methyl groups. Supra­molecular layers sustained by imine-C—H⋯O(hy­droxy), π–π [between dec­yloxy-substituted benzene rings with an inter-centroid separation of 3.7724 (13) Å], C—H⋯π(arene) and C—H⋯π(chelate ring) inter­actions are formed in the crystal; layers stack along the c axis with no directional inter­actions between them. The presence of C—H⋯π(chelate ring) inter­actions in the crystal is clearly evident from an analysis of the calculated Hirshfeld surface. International Union of Crystallography 2017-02-17 /pmc/articles/PMC5347062/ /pubmed/28316817 http://dx.doi.org/10.1107/S2056989017002365 Text en © Rosely et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Rosely, Siti Nadiah Binti Mohd
Hussen, Rusnah Syahila Duali
Lee, See Mun
Halcovitch, Nathan R.
Jotani, Mukesh M.
Tiekink, Edward R. T.
[N′-(4-Dec­yloxy-2-oxido­benzyl­idene)-3-hy­droxy-2-naphtho­hydrazidato-κ(3) N,O,O′]di­methyl­tin(IV): crystal structure and Hirshfeld surface analysis
title [N′-(4-Dec­yloxy-2-oxido­benzyl­idene)-3-hy­droxy-2-naphtho­hydrazidato-κ(3) N,O,O′]di­methyl­tin(IV): crystal structure and Hirshfeld surface analysis
title_full [N′-(4-Dec­yloxy-2-oxido­benzyl­idene)-3-hy­droxy-2-naphtho­hydrazidato-κ(3) N,O,O′]di­methyl­tin(IV): crystal structure and Hirshfeld surface analysis
title_fullStr [N′-(4-Dec­yloxy-2-oxido­benzyl­idene)-3-hy­droxy-2-naphtho­hydrazidato-κ(3) N,O,O′]di­methyl­tin(IV): crystal structure and Hirshfeld surface analysis
title_full_unstemmed [N′-(4-Dec­yloxy-2-oxido­benzyl­idene)-3-hy­droxy-2-naphtho­hydrazidato-κ(3) N,O,O′]di­methyl­tin(IV): crystal structure and Hirshfeld surface analysis
title_short [N′-(4-Dec­yloxy-2-oxido­benzyl­idene)-3-hy­droxy-2-naphtho­hydrazidato-κ(3) N,O,O′]di­methyl­tin(IV): crystal structure and Hirshfeld surface analysis
title_sort [n′-(4-dec­yloxy-2-oxido­benzyl­idene)-3-hy­droxy-2-naphtho­hydrazidato-κ(3) n,o,o′]di­methyl­tin(iv): crystal structure and hirshfeld surface analysis
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347062/
https://www.ncbi.nlm.nih.gov/pubmed/28316817
http://dx.doi.org/10.1107/S2056989017002365
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