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Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ(2) N (2),S}nickel(II): crystal structure and Hirshfeld surface analysis
The complete molecule of the title hydrazine carbodithioate complex, [Ni(C(19)H(21)N(2)S(2))(2)], is generated by the application of a centre of inversion. The Ni(II) atom is N,S-chelated by two hydrazinecarbodithioate ligands, which provide a trans-N(2)S(2) donor set that defines a distorted s...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347063/ https://www.ncbi.nlm.nih.gov/pubmed/28316818 http://dx.doi.org/10.1107/S2056989017002419 |
| _version_ | 1782513999651274752 |
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| author | Yusof, Enis Nadia Md Ravoof, Thahira B. S. A. Tahir, Mohamed I. M. Jotani, Mukesh M. Tiekink, Edward R. T. |
| author_facet | Yusof, Enis Nadia Md Ravoof, Thahira B. S. A. Tahir, Mohamed I. M. Jotani, Mukesh M. Tiekink, Edward R. T. |
| author_sort | Yusof, Enis Nadia Md |
| collection | PubMed |
| description | The complete molecule of the title hydrazine carbodithioate complex, [Ni(C(19)H(21)N(2)S(2))(2)], is generated by the application of a centre of inversion. The Ni(II) atom is N,S-chelated by two hydrazinecarbodithioate ligands, which provide a trans-N(2)S(2) donor set that defines a distorted square-planar geometry. The conformation of the five-membered chelate ring is an envelope with the Ni(II) atom being the flap atom. In the crystal, p-tolyl-C—H⋯π(benzene-(i)Pr), (i)Pr-C—H⋯π(p-tolyl) and π–π interactions [between p-tolyl rings with inter-centroid distance = 3.8051 (12) Å] help to consolidate the three-dimensional architecture. The analysis of the Hirshfeld surface confirms the importance of H-atom contacts in establishing the packing. |
| format | Online Article Text |
| id | pubmed-5347063 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2017 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-53470632017-03-17 Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ(2) N (2),S}nickel(II): crystal structure and Hirshfeld surface analysis Yusof, Enis Nadia Md Ravoof, Thahira B. S. A. Tahir, Mohamed I. M. Jotani, Mukesh M. Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Research Communications The complete molecule of the title hydrazine carbodithioate complex, [Ni(C(19)H(21)N(2)S(2))(2)], is generated by the application of a centre of inversion. The Ni(II) atom is N,S-chelated by two hydrazinecarbodithioate ligands, which provide a trans-N(2)S(2) donor set that defines a distorted square-planar geometry. The conformation of the five-membered chelate ring is an envelope with the Ni(II) atom being the flap atom. In the crystal, p-tolyl-C—H⋯π(benzene-(i)Pr), (i)Pr-C—H⋯π(p-tolyl) and π–π interactions [between p-tolyl rings with inter-centroid distance = 3.8051 (12) Å] help to consolidate the three-dimensional architecture. The analysis of the Hirshfeld surface confirms the importance of H-atom contacts in establishing the packing. International Union of Crystallography 2017-02-17 /pmc/articles/PMC5347063/ /pubmed/28316818 http://dx.doi.org/10.1107/S2056989017002419 Text en © Yusof et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| spellingShingle | Research Communications Yusof, Enis Nadia Md Ravoof, Thahira B. S. A. Tahir, Mohamed I. M. Jotani, Mukesh M. Tiekink, Edward R. T. Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ(2) N (2),S}nickel(II): crystal structure and Hirshfeld surface analysis |
| title | Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ(2)
N
(2),S}nickel(II): crystal structure and Hirshfeld surface analysis |
| title_full | Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ(2)
N
(2),S}nickel(II): crystal structure and Hirshfeld surface analysis |
| title_fullStr | Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ(2)
N
(2),S}nickel(II): crystal structure and Hirshfeld surface analysis |
| title_full_unstemmed | Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ(2)
N
(2),S}nickel(II): crystal structure and Hirshfeld surface analysis |
| title_short | Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ(2)
N
(2),S}nickel(II): crystal structure and Hirshfeld surface analysis |
| title_sort | bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ(2)
n
(2),s}nickel(ii): crystal structure and hirshfeld surface analysis |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347063/ https://www.ncbi.nlm.nih.gov/pubmed/28316818 http://dx.doi.org/10.1107/S2056989017002419 |
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