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Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene-d-ribono-1,4-lactone
In the title compound, C(15)H(16)O(6), obtained from the acylation reaction between 2,3-O-isopropylidene-d-ribono-1,4-lactone and benzoyl chloride, the known absolute configuration for the lactone moiety of the ester substituent has been confirmed. The five-membered rings of the bicyclic lactone–...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347065/ https://www.ncbi.nlm.nih.gov/pubmed/28316820 http://dx.doi.org/10.1107/S2056989017002043 |
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author | Bortoluzzi, Adailton J. Silveira, Gustavo P. Sá, Marcus M. |
author_facet | Bortoluzzi, Adailton J. Silveira, Gustavo P. Sá, Marcus M. |
author_sort | Bortoluzzi, Adailton J. |
collection | PubMed |
description | In the title compound, C(15)H(16)O(6), obtained from the acylation reaction between 2,3-O-isopropylidene-d-ribono-1,4-lactone and benzoyl chloride, the known absolute configuration for the lactone moiety of the ester substituent has been confirmed. The five-membered rings of the bicyclic lactone–dioxolane moiety both show envelope conformations and form a dihedral angle of 19.82 (7)° between the lactone ring and the benzene ring. In the crystal, molecules of the acylated sugar are linked by very weak intermolecular C—H⋯O interactions, forming a three-dimensional network. |
format | Online Article Text |
id | pubmed-5347065 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-53470652017-03-17 Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene-d-ribono-1,4-lactone Bortoluzzi, Adailton J. Silveira, Gustavo P. Sá, Marcus M. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(15)H(16)O(6), obtained from the acylation reaction between 2,3-O-isopropylidene-d-ribono-1,4-lactone and benzoyl chloride, the known absolute configuration for the lactone moiety of the ester substituent has been confirmed. The five-membered rings of the bicyclic lactone–dioxolane moiety both show envelope conformations and form a dihedral angle of 19.82 (7)° between the lactone ring and the benzene ring. In the crystal, molecules of the acylated sugar are linked by very weak intermolecular C—H⋯O interactions, forming a three-dimensional network. International Union of Crystallography 2017-02-17 /pmc/articles/PMC5347065/ /pubmed/28316820 http://dx.doi.org/10.1107/S2056989017002043 Text en © Bortoluzzi et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Bortoluzzi, Adailton J. Silveira, Gustavo P. Sá, Marcus M. Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene-d-ribono-1,4-lactone |
title | Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene-d-ribono-1,4-lactone |
title_full | Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene-d-ribono-1,4-lactone |
title_fullStr | Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene-d-ribono-1,4-lactone |
title_full_unstemmed | Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene-d-ribono-1,4-lactone |
title_short | Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene-d-ribono-1,4-lactone |
title_sort | crystal structure of 5-o-benzoyl-2,3-o-isopropylidene-d-ribono-1,4-lactone |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347065/ https://www.ncbi.nlm.nih.gov/pubmed/28316820 http://dx.doi.org/10.1107/S2056989017002043 |
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