Cargando…

Crystal structure of 5-O-benzoyl-2,3-O-iso­propyl­idene-d-ribono-1,4-lactone

In the title compound, C(15)H(16)O(6), obtained from the acyl­ation reaction between 2,3-O-iso­propyl­idene-d-ribono-1,4-lactone and benzoyl chloride, the known absolute configuration for the lactone moiety of the ester substituent has been confirmed. The five-membered rings of the bicyclic lactone–...

Descripción completa

Detalles Bibliográficos
Autores principales: Bortoluzzi, Adailton J., Silveira, Gustavo P., Sá, Marcus M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347065/
https://www.ncbi.nlm.nih.gov/pubmed/28316820
http://dx.doi.org/10.1107/S2056989017002043
_version_ 1782514000086433792
author Bortoluzzi, Adailton J.
Silveira, Gustavo P.
Sá, Marcus M.
author_facet Bortoluzzi, Adailton J.
Silveira, Gustavo P.
Sá, Marcus M.
author_sort Bortoluzzi, Adailton J.
collection PubMed
description In the title compound, C(15)H(16)O(6), obtained from the acyl­ation reaction between 2,3-O-iso­propyl­idene-d-ribono-1,4-lactone and benzoyl chloride, the known absolute configuration for the lactone moiety of the ester substituent has been confirmed. The five-membered rings of the bicyclic lactone–dioxolane moiety both show envelope conformations and form a dihedral angle of 19.82 (7)° between the lactone ring and the benzene ring. In the crystal, mol­ecules of the acyl­ated sugar are linked by very weak inter­molecular C—H⋯O inter­actions, forming a three-dimensional network.
format Online
Article
Text
id pubmed-5347065
institution National Center for Biotechnology Information
language English
publishDate 2017
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-53470652017-03-17 Crystal structure of 5-O-benzoyl-2,3-O-iso­propyl­idene-d-ribono-1,4-lactone Bortoluzzi, Adailton J. Silveira, Gustavo P. Sá, Marcus M. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(15)H(16)O(6), obtained from the acyl­ation reaction between 2,3-O-iso­propyl­idene-d-ribono-1,4-lactone and benzoyl chloride, the known absolute configuration for the lactone moiety of the ester substituent has been confirmed. The five-membered rings of the bicyclic lactone–dioxolane moiety both show envelope conformations and form a dihedral angle of 19.82 (7)° between the lactone ring and the benzene ring. In the crystal, mol­ecules of the acyl­ated sugar are linked by very weak inter­molecular C—H⋯O inter­actions, forming a three-dimensional network. International Union of Crystallography 2017-02-17 /pmc/articles/PMC5347065/ /pubmed/28316820 http://dx.doi.org/10.1107/S2056989017002043 Text en © Bortoluzzi et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Bortoluzzi, Adailton J.
Silveira, Gustavo P.
Sá, Marcus M.
Crystal structure of 5-O-benzoyl-2,3-O-iso­propyl­idene-d-ribono-1,4-lactone
title Crystal structure of 5-O-benzoyl-2,3-O-iso­propyl­idene-d-ribono-1,4-lactone
title_full Crystal structure of 5-O-benzoyl-2,3-O-iso­propyl­idene-d-ribono-1,4-lactone
title_fullStr Crystal structure of 5-O-benzoyl-2,3-O-iso­propyl­idene-d-ribono-1,4-lactone
title_full_unstemmed Crystal structure of 5-O-benzoyl-2,3-O-iso­propyl­idene-d-ribono-1,4-lactone
title_short Crystal structure of 5-O-benzoyl-2,3-O-iso­propyl­idene-d-ribono-1,4-lactone
title_sort crystal structure of 5-o-benzoyl-2,3-o-iso­propyl­idene-d-ribono-1,4-lactone
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347065/
https://www.ncbi.nlm.nih.gov/pubmed/28316820
http://dx.doi.org/10.1107/S2056989017002043
work_keys_str_mv AT bortoluzziadailtonj crystalstructureof5obenzoyl23oisopropylidenedribono14lactone
AT silveiragustavop crystalstructureof5obenzoyl23oisopropylidenedribono14lactone
AT samarcusm crystalstructureof5obenzoyl23oisopropylidenedribono14lactone