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Bis(μ(2)-N-methyl-N-phenyldithiocarbamato)-κ(3) S,S′:S;κ(3) S:S,S′-bis[(N-methyl-N-phenyldithiocarbamato-κ(2) S,S′)cadmium]: crystal structure and Hirshfeld surface analysis
The title compound, [Cd(2)(C(8)H(8)NS(2))(4)], is a centrosymmetric dimer with both chelating and μ(2)-tridentate dithiocarbamate ligands. The resulting S(5) donor set defines a Cd(II) coordination geometry intermediate between square-pyramidal and trigonal–bipyramidal, but tending towards the fo...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347070/ https://www.ncbi.nlm.nih.gov/pubmed/28316825 http://dx.doi.org/10.1107/S2056989017002705 |
| _version_ | 1782514001231478784 |
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| author | Suwardi, Siti Aisyah Nabilah Lee, See Mun Lo, Kong Mun Jotani, Mukesh M. Tiekink, Edward R. T. |
| author_facet | Suwardi, Siti Aisyah Nabilah Lee, See Mun Lo, Kong Mun Jotani, Mukesh M. Tiekink, Edward R. T. |
| author_sort | Suwardi, Siti Aisyah Nabilah |
| collection | PubMed |
| description | The title compound, [Cd(2)(C(8)H(8)NS(2))(4)], is a centrosymmetric dimer with both chelating and μ(2)-tridentate dithiocarbamate ligands. The resulting S(5) donor set defines a Cd(II) coordination geometry intermediate between square-pyramidal and trigonal–bipyramidal, but tending towards the former. The packing features C—H⋯S and C—H⋯π interactions, which generate a three-dimensional network. The influence of these interactions, along with intra-dimer π–π interactions between chelate rings, has been investigated by an analysis of the Hirshfeld surface. |
| format | Online Article Text |
| id | pubmed-5347070 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2017 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-53470702017-03-17 Bis(μ(2)-N-methyl-N-phenyldithiocarbamato)-κ(3) S,S′:S;κ(3) S:S,S′-bis[(N-methyl-N-phenyldithiocarbamato-κ(2) S,S′)cadmium]: crystal structure and Hirshfeld surface analysis Suwardi, Siti Aisyah Nabilah Lee, See Mun Lo, Kong Mun Jotani, Mukesh M. Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Cd(2)(C(8)H(8)NS(2))(4)], is a centrosymmetric dimer with both chelating and μ(2)-tridentate dithiocarbamate ligands. The resulting S(5) donor set defines a Cd(II) coordination geometry intermediate between square-pyramidal and trigonal–bipyramidal, but tending towards the former. The packing features C—H⋯S and C—H⋯π interactions, which generate a three-dimensional network. The influence of these interactions, along with intra-dimer π–π interactions between chelate rings, has been investigated by an analysis of the Hirshfeld surface. International Union of Crystallography 2017-02-21 /pmc/articles/PMC5347070/ /pubmed/28316825 http://dx.doi.org/10.1107/S2056989017002705 Text en © Suwardi et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| spellingShingle | Research Communications Suwardi, Siti Aisyah Nabilah Lee, See Mun Lo, Kong Mun Jotani, Mukesh M. Tiekink, Edward R. T. Bis(μ(2)-N-methyl-N-phenyldithiocarbamato)-κ(3) S,S′:S;κ(3) S:S,S′-bis[(N-methyl-N-phenyldithiocarbamato-κ(2) S,S′)cadmium]: crystal structure and Hirshfeld surface analysis |
| title | Bis(μ(2)-N-methyl-N-phenyldithiocarbamato)-κ(3)
S,S′:S;κ(3)
S:S,S′-bis[(N-methyl-N-phenyldithiocarbamato-κ(2)
S,S′)cadmium]: crystal structure and Hirshfeld surface analysis |
| title_full | Bis(μ(2)-N-methyl-N-phenyldithiocarbamato)-κ(3)
S,S′:S;κ(3)
S:S,S′-bis[(N-methyl-N-phenyldithiocarbamato-κ(2)
S,S′)cadmium]: crystal structure and Hirshfeld surface analysis |
| title_fullStr | Bis(μ(2)-N-methyl-N-phenyldithiocarbamato)-κ(3)
S,S′:S;κ(3)
S:S,S′-bis[(N-methyl-N-phenyldithiocarbamato-κ(2)
S,S′)cadmium]: crystal structure and Hirshfeld surface analysis |
| title_full_unstemmed | Bis(μ(2)-N-methyl-N-phenyldithiocarbamato)-κ(3)
S,S′:S;κ(3)
S:S,S′-bis[(N-methyl-N-phenyldithiocarbamato-κ(2)
S,S′)cadmium]: crystal structure and Hirshfeld surface analysis |
| title_short | Bis(μ(2)-N-methyl-N-phenyldithiocarbamato)-κ(3)
S,S′:S;κ(3)
S:S,S′-bis[(N-methyl-N-phenyldithiocarbamato-κ(2)
S,S′)cadmium]: crystal structure and Hirshfeld surface analysis |
| title_sort | bis(μ(2)-n-methyl-n-phenyldithiocarbamato)-κ(3)
s,s′:s;κ(3)
s:s,s′-bis[(n-methyl-n-phenyldithiocarbamato-κ(2)
s,s′)cadmium]: crystal structure and hirshfeld surface analysis |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347070/ https://www.ncbi.nlm.nih.gov/pubmed/28316825 http://dx.doi.org/10.1107/S2056989017002705 |
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