Crystal structure of Li(3)Ga(BO(3))(2)

The crystal structure of trilithium gallium bis­(orthoborate), Li(3)Ga(BO(3))(2), is isotypic with Li(3)Al(BO(3))(2) in a triclinic cell in space-group type P-1. The three Li and the unique Ga atom are coordinated by four O atoms each in tetra­hedra, and the two B atoms are coordinated by three O at...

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Detalles Bibliográficos
Autores principales: Smith, Robert W., Holman, Darien, Villa, Eric M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347076/
https://www.ncbi.nlm.nih.gov/pubmed/28316831
http://dx.doi.org/10.1107/S205698901700295X
Descripción
Sumario:The crystal structure of trilithium gallium bis­(orthoborate), Li(3)Ga(BO(3))(2), is isotypic with Li(3)Al(BO(3))(2) in a triclinic cell in space-group type P-1. The three Li and the unique Ga atom are coordinated by four O atoms each in tetra­hedra, and the two B atoms are coordinated by three O atoms in orthoborate triangles. Chains with composition [Ga(2)(BO(3))(4)](6−) extend along the a axis. The Li atoms inter­leave these chains in tetra­hedral inter­stices. A comparison is made between the structure model of the title compound and that of a previously reported model for a compound with the same composition [Abdullaev & Mamedov (1972 ▸). Zh. Strukt. Khim. 13, 943–946.]

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