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Crystal structure of Li(3)Ga(BO(3))(2)
The crystal structure of trilithium gallium bis(orthoborate), Li(3)Ga(BO(3))(2), is isotypic with Li(3)Al(BO(3))(2) in a triclinic cell in space-group type P-1. The three Li and the unique Ga atom are coordinated by four O atoms each in tetrahedra, and the two B atoms are coordinated by three O at...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347076/ https://www.ncbi.nlm.nih.gov/pubmed/28316831 http://dx.doi.org/10.1107/S205698901700295X |
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| author | Smith, Robert W. Holman, Darien Villa, Eric M. |
| author_facet | Smith, Robert W. Holman, Darien Villa, Eric M. |
| author_sort | Smith, Robert W. |
| collection | PubMed |
| description | The crystal structure of trilithium gallium bis(orthoborate), Li(3)Ga(BO(3))(2), is isotypic with Li(3)Al(BO(3))(2) in a triclinic cell in space-group type P-1. The three Li and the unique Ga atom are coordinated by four O atoms each in tetrahedra, and the two B atoms are coordinated by three O atoms in orthoborate triangles. Chains with composition [Ga(2)(BO(3))(4)](6−) extend along the a axis. The Li atoms interleave these chains in tetrahedral interstices. A comparison is made between the structure model of the title compound and that of a previously reported model for a compound with the same composition [Abdullaev & Mamedov (1972 ▸). Zh. Strukt. Khim. 13, 943–946.] |
| format | Online Article Text |
| id | pubmed-5347076 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2017 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-53470762017-03-17 Crystal structure of Li(3)Ga(BO(3))(2) Smith, Robert W. Holman, Darien Villa, Eric M. Acta Crystallogr E Crystallogr Commun Research Communications The crystal structure of trilithium gallium bis(orthoborate), Li(3)Ga(BO(3))(2), is isotypic with Li(3)Al(BO(3))(2) in a triclinic cell in space-group type P-1. The three Li and the unique Ga atom are coordinated by four O atoms each in tetrahedra, and the two B atoms are coordinated by three O atoms in orthoborate triangles. Chains with composition [Ga(2)(BO(3))(4)](6−) extend along the a axis. The Li atoms interleave these chains in tetrahedral interstices. A comparison is made between the structure model of the title compound and that of a previously reported model for a compound with the same composition [Abdullaev & Mamedov (1972 ▸). Zh. Strukt. Khim. 13, 943–946.] International Union of Crystallography 2017-02-28 /pmc/articles/PMC5347076/ /pubmed/28316831 http://dx.doi.org/10.1107/S205698901700295X Text en © Smith et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| spellingShingle | Research Communications Smith, Robert W. Holman, Darien Villa, Eric M. Crystal structure of Li(3)Ga(BO(3))(2) |
| title | Crystal structure of Li(3)Ga(BO(3))(2)
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| title_full | Crystal structure of Li(3)Ga(BO(3))(2)
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| title_fullStr | Crystal structure of Li(3)Ga(BO(3))(2)
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| title_full_unstemmed | Crystal structure of Li(3)Ga(BO(3))(2)
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| title_short | Crystal structure of Li(3)Ga(BO(3))(2)
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| title_sort | crystal structure of li(3)ga(bo(3))(2) |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347076/ https://www.ncbi.nlm.nih.gov/pubmed/28316831 http://dx.doi.org/10.1107/S205698901700295X |
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