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Crystal structure of (2,2′-bipyridine-κ(2) N,N′)bis(3,5-di-tert-butyl-o-benzoquinonato-κ(2) O,O′)ruthenium(II)
In the title mononuclear complex, [Ru(C(14)H(20)O(2))(2)(C(10)H(8)N(2))], the Ru(II) ion has a distorted octahedral coordination environment defined by two N atoms of the chelating 2,2′-bipyridine ligand and four O atoms from two 3,5-di-tert-butyl-o-benzoquinone ligands. In the crystal, the compl...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347077/ https://www.ncbi.nlm.nih.gov/pubmed/28316832 http://dx.doi.org/10.1107/S205698901700281X |
| _version_ | 1782514002828460032 |
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| author | Faizi, Md. Serajul Haque Ali, Akram Potaskalov, Vadim A. |
| author_facet | Faizi, Md. Serajul Haque Ali, Akram Potaskalov, Vadim A. |
| author_sort | Faizi, Md. Serajul Haque |
| collection | PubMed |
| description | In the title mononuclear complex, [Ru(C(14)H(20)O(2))(2)(C(10)H(8)N(2))], the Ru(II) ion has a distorted octahedral coordination environment defined by two N atoms of the chelating 2,2′-bipyridine ligand and four O atoms from two 3,5-di-tert-butyl-o-benzoquinone ligands. In the crystal, the complex molecules are linked by intermolecular C—H⋯O hydrogen bonds and π–π stacking interactions between the 2,2′-bipyridine ligands [centroid–centroid distance = 3.538 (3) Å], resulting in a layer structure extending parallel to the ab plane. |
| format | Online Article Text |
| id | pubmed-5347077 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2017 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-53470772017-03-17 Crystal structure of (2,2′-bipyridine-κ(2) N,N′)bis(3,5-di-tert-butyl-o-benzoquinonato-κ(2) O,O′)ruthenium(II) Faizi, Md. Serajul Haque Ali, Akram Potaskalov, Vadim A. Acta Crystallogr E Crystallogr Commun Research Communications In the title mononuclear complex, [Ru(C(14)H(20)O(2))(2)(C(10)H(8)N(2))], the Ru(II) ion has a distorted octahedral coordination environment defined by two N atoms of the chelating 2,2′-bipyridine ligand and four O atoms from two 3,5-di-tert-butyl-o-benzoquinone ligands. In the crystal, the complex molecules are linked by intermolecular C—H⋯O hydrogen bonds and π–π stacking interactions between the 2,2′-bipyridine ligands [centroid–centroid distance = 3.538 (3) Å], resulting in a layer structure extending parallel to the ab plane. International Union of Crystallography 2017-02-28 /pmc/articles/PMC5347077/ /pubmed/28316832 http://dx.doi.org/10.1107/S205698901700281X Text en © Faizi et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| spellingShingle | Research Communications Faizi, Md. Serajul Haque Ali, Akram Potaskalov, Vadim A. Crystal structure of (2,2′-bipyridine-κ(2) N,N′)bis(3,5-di-tert-butyl-o-benzoquinonato-κ(2) O,O′)ruthenium(II) |
| title | Crystal structure of (2,2′-bipyridine-κ(2)
N,N′)bis(3,5-di-tert-butyl-o-benzoquinonato-κ(2)
O,O′)ruthenium(II) |
| title_full | Crystal structure of (2,2′-bipyridine-κ(2)
N,N′)bis(3,5-di-tert-butyl-o-benzoquinonato-κ(2)
O,O′)ruthenium(II) |
| title_fullStr | Crystal structure of (2,2′-bipyridine-κ(2)
N,N′)bis(3,5-di-tert-butyl-o-benzoquinonato-κ(2)
O,O′)ruthenium(II) |
| title_full_unstemmed | Crystal structure of (2,2′-bipyridine-κ(2)
N,N′)bis(3,5-di-tert-butyl-o-benzoquinonato-κ(2)
O,O′)ruthenium(II) |
| title_short | Crystal structure of (2,2′-bipyridine-κ(2)
N,N′)bis(3,5-di-tert-butyl-o-benzoquinonato-κ(2)
O,O′)ruthenium(II) |
| title_sort | crystal structure of (2,2′-bipyridine-κ(2)
n,n′)bis(3,5-di-tert-butyl-o-benzoquinonato-κ(2)
o,o′)ruthenium(ii) |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347077/ https://www.ncbi.nlm.nih.gov/pubmed/28316832 http://dx.doi.org/10.1107/S205698901700281X |
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