Iminophosphanes: Synthesis, Rhodium Complexes, and Ruthenium(II)-Catalyzed Hydration of Nitriles

[Image: see text] Highly stable iminophosphanes, obtained from alkylating nitriles and reaction of the resulting nitrilium ions with secondary phosphanes, were explored as tunable P-monodentate and 1,3-P,N bidentate ligands in rhodium complexes. X-ray crystal structures are reported for both κ(1) an...

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Autores principales: Rong, Mark K., van Duin, Koen, van Dijk, Tom, de Pater, Jeroen J. M., Deelman, Berth-Jan, Nieger, Martin, Ehlers, A. W., Slootweg, J. Chris, Lammertsma, Koop
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5350608/
https://www.ncbi.nlm.nih.gov/pubmed/28316361
http://dx.doi.org/10.1021/acs.organomet.7b00057

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