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C(sp(3))–C(sp(2)) cross-coupling of alkylsilicates with borylated aryl bromides – an iterative platform to alkylated aryl- and heteroaryl boronates

The attractive field of iterative cross-coupling has seen numerous advances, although almost exclusively in the union of sp(2)-hybridized partners. Conspicuously absent from this useful synthetic manifold is the inclusion of sp(3)-hybridized pronucleophiles that can undergo transmetalation under mil...

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Detalles Bibliográficos
Autores principales: Vara, Brandon A., Jouffroy, Matthieu, Molander, Gary A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5351799/
https://www.ncbi.nlm.nih.gov/pubmed/28451200
http://dx.doi.org/10.1039/c6sc03236b