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C(sp(3))–C(sp(2)) cross-coupling of alkylsilicates with borylated aryl bromides – an iterative platform to alkylated aryl- and heteroaryl boronates
The attractive field of iterative cross-coupling has seen numerous advances, although almost exclusively in the union of sp(2)-hybridized partners. Conspicuously absent from this useful synthetic manifold is the inclusion of sp(3)-hybridized pronucleophiles that can undergo transmetalation under mil...
Autores principales: | Vara, Brandon A., Jouffroy, Matthieu, Molander, Gary A. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5351799/ https://www.ncbi.nlm.nih.gov/pubmed/28451200 http://dx.doi.org/10.1039/c6sc03236b |
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