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Raman and Luminescent Spectra of Sulfonated Zn Phthalocyanine Enhanced by Gold Nanoparticles

Sulfonated Zn phthalocyanine, as a prospective photosensitizer in the photodynamic therapy of tumors, is investigated by means of Raman, infrared, and fluorescence spectroscopies. Conventional and surface-enhanced spectra from this photosensitizer are obtained and compared. Gold nano-islands attache...

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Autores principales: Kavelin, V., Fesenko, O., Dubyna, H., Vidal, C., Klar, T. A., Hrelescu, C., Dolgov, L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5355401/
https://www.ncbi.nlm.nih.gov/pubmed/28314363
http://dx.doi.org/10.1186/s11671-017-1972-5
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author Kavelin, V.
Fesenko, O.
Dubyna, H.
Vidal, C.
Klar, T. A.
Hrelescu, C.
Dolgov, L.
author_facet Kavelin, V.
Fesenko, O.
Dubyna, H.
Vidal, C.
Klar, T. A.
Hrelescu, C.
Dolgov, L.
author_sort Kavelin, V.
collection PubMed
description Sulfonated Zn phthalocyanine, as a prospective photosensitizer in the photodynamic therapy of tumors, is investigated by means of Raman, infrared, and fluorescence spectroscopies. Conventional and surface-enhanced spectra from this photosensitizer are obtained and compared. Gold nano-islands attached to silica cores (Au-SiO(2)) are proposed as nanostructures providing plasmonically enhanced signals. Pronounced enhancement of Raman and infrared spectral bands from sulfonated Zn phthalocyanine allows their more convenient assignment with vibrational modes of sulfonated Zn phthalocyanine. In comparison to Raman and IR, the fluorescence is less enhanced by Au-SiO(2) particles.
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spelling pubmed-53554012017-03-30 Raman and Luminescent Spectra of Sulfonated Zn Phthalocyanine Enhanced by Gold Nanoparticles Kavelin, V. Fesenko, O. Dubyna, H. Vidal, C. Klar, T. A. Hrelescu, C. Dolgov, L. Nanoscale Res Lett Nano Express Sulfonated Zn phthalocyanine, as a prospective photosensitizer in the photodynamic therapy of tumors, is investigated by means of Raman, infrared, and fluorescence spectroscopies. Conventional and surface-enhanced spectra from this photosensitizer are obtained and compared. Gold nano-islands attached to silica cores (Au-SiO(2)) are proposed as nanostructures providing plasmonically enhanced signals. Pronounced enhancement of Raman and infrared spectral bands from sulfonated Zn phthalocyanine allows their more convenient assignment with vibrational modes of sulfonated Zn phthalocyanine. In comparison to Raman and IR, the fluorescence is less enhanced by Au-SiO(2) particles. Springer US 2017-03-16 /pmc/articles/PMC5355401/ /pubmed/28314363 http://dx.doi.org/10.1186/s11671-017-1972-5 Text en © The Author(s). 2017 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
spellingShingle Nano Express
Kavelin, V.
Fesenko, O.
Dubyna, H.
Vidal, C.
Klar, T. A.
Hrelescu, C.
Dolgov, L.
Raman and Luminescent Spectra of Sulfonated Zn Phthalocyanine Enhanced by Gold Nanoparticles
title Raman and Luminescent Spectra of Sulfonated Zn Phthalocyanine Enhanced by Gold Nanoparticles
title_full Raman and Luminescent Spectra of Sulfonated Zn Phthalocyanine Enhanced by Gold Nanoparticles
title_fullStr Raman and Luminescent Spectra of Sulfonated Zn Phthalocyanine Enhanced by Gold Nanoparticles
title_full_unstemmed Raman and Luminescent Spectra of Sulfonated Zn Phthalocyanine Enhanced by Gold Nanoparticles
title_short Raman and Luminescent Spectra of Sulfonated Zn Phthalocyanine Enhanced by Gold Nanoparticles
title_sort raman and luminescent spectra of sulfonated zn phthalocyanine enhanced by gold nanoparticles
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5355401/
https://www.ncbi.nlm.nih.gov/pubmed/28314363
http://dx.doi.org/10.1186/s11671-017-1972-5
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