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A concerted two-prong approach to the in situ allosteric regulation of bifunctional catalysis
Herein, we report the reversible in situ “on–off” allosteric regulation of hydrogen-bond-donating (HBD)–Lewis base co-catalytic activity via a concerted two-prong methodology entailing cooperative acid–base chemistry and a structurally addressable coordination complex. Specifically, a heteroligated...
Autores principales: | McGuirk, C. Michael, Mendez-Arroyo, Jose, d'Aquino, Andrea I., Stern, Charlotte L., Liu, Yuan, Mirkin, Chad A. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5355828/ https://www.ncbi.nlm.nih.gov/pubmed/28451109 http://dx.doi.org/10.1039/c6sc01454b |
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