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A general derivation and quantification of the third law of thermodynamics

The most accepted version of the third law of thermodynamics, the unattainability principle, states that any process cannot reach absolute zero temperature in a finite number of steps and within a finite time. Here, we provide a derivation of the principle that applies to arbitrary cooling processes...

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Detalles Bibliográficos
Autores principales: Masanes, Lluís, Oppenheim, Jonathan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5355879/
https://www.ncbi.nlm.nih.gov/pubmed/28290452
http://dx.doi.org/10.1038/ncomms14538
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author Masanes, Lluís
Oppenheim, Jonathan
author_facet Masanes, Lluís
Oppenheim, Jonathan
author_sort Masanes, Lluís
collection PubMed
description The most accepted version of the third law of thermodynamics, the unattainability principle, states that any process cannot reach absolute zero temperature in a finite number of steps and within a finite time. Here, we provide a derivation of the principle that applies to arbitrary cooling processes, even those exploiting the laws of quantum mechanics or involving an infinite-dimensional reservoir. We quantify the resources needed to cool a system to any temperature, and translate these resources into the minimal time or number of steps, by considering the notion of a thermal machine that obeys similar restrictions to universal computers. We generally find that the obtainable temperature can scale as an inverse power of the cooling time. Our results also clarify the connection between two versions of the third law (the unattainability principle and the heat theorem), and place ultimate bounds on the speed at which information can be erased.
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spelling pubmed-53558792017-04-17 A general derivation and quantification of the third law of thermodynamics Masanes, Lluís Oppenheim, Jonathan Nat Commun Article The most accepted version of the third law of thermodynamics, the unattainability principle, states that any process cannot reach absolute zero temperature in a finite number of steps and within a finite time. Here, we provide a derivation of the principle that applies to arbitrary cooling processes, even those exploiting the laws of quantum mechanics or involving an infinite-dimensional reservoir. We quantify the resources needed to cool a system to any temperature, and translate these resources into the minimal time or number of steps, by considering the notion of a thermal machine that obeys similar restrictions to universal computers. We generally find that the obtainable temperature can scale as an inverse power of the cooling time. Our results also clarify the connection between two versions of the third law (the unattainability principle and the heat theorem), and place ultimate bounds on the speed at which information can be erased. Nature Publishing Group 2017-03-14 /pmc/articles/PMC5355879/ /pubmed/28290452 http://dx.doi.org/10.1038/ncomms14538 Text en Copyright © 2017, The Author(s) http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article's Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Masanes, Lluís
Oppenheim, Jonathan
A general derivation and quantification of the third law of thermodynamics
title A general derivation and quantification of the third law of thermodynamics
title_full A general derivation and quantification of the third law of thermodynamics
title_fullStr A general derivation and quantification of the third law of thermodynamics
title_full_unstemmed A general derivation and quantification of the third law of thermodynamics
title_short A general derivation and quantification of the third law of thermodynamics
title_sort general derivation and quantification of the third law of thermodynamics
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5355879/
https://www.ncbi.nlm.nih.gov/pubmed/28290452
http://dx.doi.org/10.1038/ncomms14538
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