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A computational triage approach to the synthesis of novel difluorocyclopentenes and fluorinated cycloheptadienes using thermal rearrangements

Electronic structure calculations have been used for the effective triage of substituent effects on difluorinated vinylcyclopropane precursors and their ability to undergo vinyl cyclopropane rearrangements (VCPR). Groups which effectively stabilised radicals, specifically heteroarenes, were found to...

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Detalles Bibliográficos
Autores principales: Orr, David, Percy, Jonathan M., Harrison, Zoë A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5355944/
https://www.ncbi.nlm.nih.gov/pubmed/28451092
http://dx.doi.org/10.1039/c6sc01289b

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