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Cycloheptatrienyl trianion: an elusive bridge in the search of exchange coupled dinuclear organolanthanide single-molecule magnets

The preparation of η-cyclopentadienyl (η(5)-C(5)R(5)), η-arene (η(6)-C(6)R(6)), and η-cyclooctatetraenyl (η(8)-C(8)R(8)) bridging motifs are common in organometallic chemistry; however, the synthetic preparation of η-cycloheptatrienyl (η(7)-C(7)R(7)) bridging motifs has remained a synthetic challeng...

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Detalles Bibliográficos
Autores principales: Harriman, Katie L. M., Le Roy, Jennifer J., Ungur, Liviu, Holmberg, Rebecca J., Korobkov, Ilia, Murugesu, Muralee
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5355948/
https://www.ncbi.nlm.nih.gov/pubmed/28451170
http://dx.doi.org/10.1039/c6sc01224h