Cargando…
N-heterocyclic carbene induced reductive coupling of phosphorus tribromide. Isolation of a bromine bridged P–P bond and its subsequent reactivity
The room temperature reaction of a 1 : 1 mixture of phosphorus tribromide (PBr(3)) and the N-heterocyclic carbene 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene (IPr) quantitatively affords the Lewis acid–base adduct (IPr)PBr(3) (1). Interestingly, when 1 is heated between 55 and 65 °C for a peri...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5356258/ https://www.ncbi.nlm.nih.gov/pubmed/28451133 http://dx.doi.org/10.1039/c6sc02343f |