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Catalytic, Enantioselective, Intramolecular Sulfenofunctionalization of Alkenes with Phenols
[Image: see text] The catalytic, enantioselective, cyclization of phenols with electrophilic sulfenophthalimides onto isolated or conjugated alkenes affords 2,3-disubstituted benzopyrans and benzoxepins. The reaction is catalyzed by a BINAM-based phosphoramide Lewis base catalyst which assists in th...
Autores principales: | Denmark, Scott E., Kornfilt, David J. P. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2017
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5360160/ https://www.ncbi.nlm.nih.gov/pubmed/28257203 http://dx.doi.org/10.1021/acs.joc.7b00295 |
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