Cargando…
Metal-free O–H/C–H difunctionalization of phenols by o-hydroxyarylsulfonium salts in water
An environmentally benign method for C–H/O–H difunctionalization of phenols with sulfoxides under mild conditions has been developed. The reaction process is mediated by an electrophilic aromatic substitution and subsequent selective aryl or alkyl migration, involving C–S and C–O bond formations wit...
Autores principales: | Chen, Dengfeng, Feng, Qingyuan, Yang, Yunqin, Cai, Xu-Min, Wang, Fei, Huang, Shenlin |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5361865/ https://www.ncbi.nlm.nih.gov/pubmed/28451289 http://dx.doi.org/10.1039/c6sc04504a |
Ejemplares similares
-
Overcoming O–H Insertion to Para-Selective
C–H Functionalization of Free Phenols: Rh(II)/Xantphos
Catalyzed Geminal Difunctionalization of Diazo Compounds
por: Yang, Yang, et al.
Publicado: (2022) -
One-Pot Difunctionalization of Aryldiazonium Salts for Synthesis of para-Azophenols
por: Liu, Zhenhua, et al.
Publicado: (2022) -
Walking metals: catalytic difunctionalization of alkenes at nonclassical sites
por: Dhungana, Roshan K., et al.
Publicado: (2020) -
Transition‐Metal‐Free Difunctionalization of Sulfur Nucleophiles
por: Mondal, Shobhan, et al.
Publicado: (2023) -
Photoredox radical/polar crossover enables C–H gem-difunctionalization of 1,3-benzodioxoles for the synthesis of monofluorocyclohexenes
por: Tian, Jiabao, et al.
Publicado: (2023)