Cargando…
Using Ylide Functionalization to Stabilize Boron Cations
The metalated ylide YNa [Y=(Ph(3)PCSO(2)Tol)(−)] was employed as X,L‐donor ligand for the preparation of a series of boron cations. Treatment of the bis‐ylide functionalized borane Y(2)BH with different trityl salts or B(C(6)F(5))(3) for hydride abstraction readily results in the formation of the bi...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2017
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5363341/ https://www.ncbi.nlm.nih.gov/pubmed/28185370 http://dx.doi.org/10.1002/anie.201611677 |