Cargando…

Exploring secondary-sphere interactions in Fe–N( x )H( y ) complexes relevant to N(2) fixation

Hydrogen bonding and other types of secondary-sphere interactions are ubiquitous in metalloenzyme active sites and are critical to the transformations they mediate. Exploiting secondary sphere interactions in synthetic catalysts to study the role(s) they might play in biological systems, and to deve...

Descripción completa

Detalles Bibliográficos
Autores principales:	Creutz, Sidney E., Peters, Jonas C.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5363375/ https://www.ncbi.nlm.nih.gov/pubmed/28451336 http://dx.doi.org/10.1039/c6sc04805f

Ejemplares similares

Electrophile-promoted Fe-to-N(2) hydride migration in highly reduced Fe(N(2))(H) complexes
por: Deegan, Meaghan M., et al.
Publicado: (2018)

Intramolecular N–H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl(2) complex
por: Gavette, Jesse V., et al.
Publicado: (2014)

Fe, N-doped carbon spheres prepared by electrospinning method as high efficiency oxygen reduction catalyst
por: Zou, Hanzeng, et al.
Publicado: (2020)

Facile construction of Fe, N and P co-doped carbon spheres by carbothermal strategy for the adsorption and reduction of U(vi)
por: Dong, Zhimin, et al.
Publicado: (2020)

Predicting viable isomers of [X,C,N] and [H,X,C,N] (X = Sn, Pb)
por: Sun, Yu-Wang, et al.
Publicado: (2019)

Redox tuning of the H-cluster by second coordination sphere amino acids in the sensory [FeFe] hydrogenase from Thermotoga maritima
por: Chongdar, Nipa, et al.
Publicado: (2023)

Second-sphere effects on H(2)O(2) activation by non-heme Fe(II) complexes: role of a phenol group in the [H(2)O(2)]-dependent accumulation of Fe(IV)O vs. Fe(III)OOH
por: Rebilly, Jean-Noël, et al.
Publicado: (2021)

Glycerine-based synthesis of a highly efficient Fe(2)O(3) electrocatalyst for N(2) fixation
por: Wang, Meng, et al.
Publicado: (2020)

Snapshots of magnesium-centred diborane heterolysis by an outer sphere S(N)2 process
por: Pécharman, Anne-Frédérique, et al.
Publicado: (2019)

Fe(II)-catalysed insertion reaction of α-diazocarbonyls into X–H bonds (X = Si, S, N, and O) in dimethyl carbonate as a suitable solvent alternative
por: Tanbouza, Nour, et al.
Publicado: (2019)

Systematic exploration of N, C configurational effects on the ORR performance of Fe–N doped graphene catalysts based on DFT calculations
por: Liu, Fan, et al.
Publicado: (2019)

C−X (X = N, O) Cross-Coupling Reactions Catalyzed by Copper-Pincer Bis(N-Heterocyclic Carbene) Complexes
por: Minnick, Jennifer L., et al.
Publicado: (2019)

A pendant proton shuttle on [Fe(4)N(CO)(12)](–) alters product selectivity in formate vs. H(2) production via the hydride [H–Fe(4)N(CO)(12)](–)
por: Loewen, Natalia D., et al.
Publicado: (2016)

Synergistic catalysis on Fe–N(x) sites and Fe nanoparticles for efficient synthesis of quinolines and quinazolinones via oxidative coupling of amines and aldehydes
por: Ma, Zhiming, et al.
Publicado: (2019)

Micron-sized SiO(x)/N-doped carbon composite spheres fabricated with biomass chitosan for high-performance lithium-ion battery anodes
por: Liu, Dajin, et al.
Publicado: (2020)

Influence of coordination structure of Fe-585DV/N(x)C(4−x) on the electrocatalytic performance of oxygen reduction reactions
por: Li, Ren, et al.
Publicado: (2023)

Near-infrared electroluminescence beyond 940 nm in Pt(N^C^N)X complexes: influencing aggregation with the ancillary ligand X
por: Salthouse, Rebecca J., et al.
Publicado: (2022)

Reversible coordination of N(2) and H(2) to a homoleptic S = 1/2 Fe(i) diphosphine complex in solution and the solid state
por: Doyle, Laurence R., et al.
Publicado: (2018)

Secondary-Sphere Effects in Molecular Electrocatalytic CO(2) Reduction
por: Nichols, Asa W., et al.
Publicado: (2019)

Hierarchically porous carbons as supports for fuel cell electrocatalysts with atomically dispersed Fe–N(x) moieties
por: Tong, Lei, et al.
Publicado: (2019)

Anion control of tautomeric equilibria: Fe–H vs. N–H influenced by NH···F hydrogen bonding
por: Chambers, Geoffrey M., et al.
Publicado: (2018)

Correction: Synergistic catalysis on Fe–N(x) sites and Fe nanoparticles for efficient synthesis of quinolines and quinazolinones via oxidative coupling of amines and aldehydes
por: Ma, Zhiming, et al.
Publicado: (2019)

Degradation and regeneration of Fe–N(x) active sites for the oxygen reduction reaction: the role of surface oxidation, Fe demetallation and local carbon microporosity
por: Xia, Dongsheng, et al.
Publicado: (2021)

Ni(II) and Cu(II) complexes of a salen ligand bearing ferrocenes in its secondary coordination sphere
por: Sailer, Rachel, et al.
Publicado: (2023)

Hollow terbium metal–organic-framework spheres: preparation and their performance in Fe(3+) detection
por: Yang, Xiaozhan, et al.
Publicado: (2022)

Exploring a new dinuclear Fe(iii) complex for the fixation of atmospheric CO(2) and optical recognition of nano-molar levels of Zn(2+) ions
por: Taniya, Seikh, et al.
Publicado: (2020)

N/S co-doped coal-based porous carbon spheres as electrode materials for high performance supercapacitors
por: Lv, Yan, et al.
Publicado: (2020)

Ultrafine Ru nanoclusters supported on N/S doped macroporous carbon spheres for efficient hydrogen evolution reaction
por: Wang, Yijie, et al.
Publicado: (2021)

Hydride state accumulation in native [FeFe]-hydrogenase with the physiological reductant H(2) supports its catalytic relevance
por: Senger, Moritz, et al.
Publicado: (2022)

Pd(12)M(n)L(24) (for n = 6, 8, 12) nanospheres by post-assembly modification of Pd(12)L(24) spheres
por: Bobylev, Eduard. O., et al.
Publicado: (2023)

The self-template synthesis of highly efficient hollow structure Fe/N/C electrocatalysts with Fe–N coordination for the oxygen reduction reaction
por: Yu, Yue, et al.
Publicado: (2018)

Exploring room-temperature ferromagnetism in WXBC (X = W, Mn, Fe) monolayers
por: Abdullahi, Yusuf Zuntu, et al.
Publicado: (2022)

Tunable and convenient synthesis of highly dispersed Fe–N(x) catalysts from graphene-supported Zn–Fe-ZIF for efficient oxygen reduction in acidic media
por: Yang, Limeng, et al.
Publicado: (2019)

Mechanism of atom economical conversion of alcohols and amines to amides using Fe(ii) pincer catalyst. An outer-sphere metal–ligand pathway or an inner-sphere elimination pathway?
por: Shiekh, Bilal Ahmad, et al.
Publicado: (2019)

N-doped graphene/CoFe(2)O(4) catalysts for the selective catalytic reduction of NO(x) by NH(3)
por: Li, Peng, et al.
Publicado: (2019)

Fe(iii)-catalysed selective C–N bond cleavage of N-phenylamides by an electrochemical method
por: Xu, Yiwen, et al.
Publicado: (2022)

Thin film encapsulation for quantum dot light-emitting diodes using a-SiN(x):H/SiO(x)N(y)/hybrid SiO(x) barriers
por: Lim, Keun Yong, et al.
Publicado: (2022)

B(12)X(11)(H(2))(−): exploring the limits of isotopologue selectivity of hydrogen adsorption
por: Wulf, Toshiki, et al.
Publicado: (2021)

A DFT study on the C–H oxidation reactivity of Fe(iv)–oxo species with N4/N5 ligands derived from l-proline
por: Lin, Jin, et al.
Publicado: (2021)

Influence of intramolecular secondary sphere hydrogen-bonding interactions on cytochrome c oxidase inspired low-spin heme–peroxo–copper complexes
por: Ehudin, Melanie A., et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_edj64pm7joc48racp6o2085tog