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Photochemical pump and NMR probe to monitor the formation and kinetics of hyperpolarized metal dihydrides
On reaction of IrI(CO)(PPh(3))(2) 1 with para-hydrogen (p-H(2)), Ir(H)(2)I(CO)(PPh(3))(2) 2 is formed which exhibits strongly enhanced (1)H NMR signals for its hydride resonances. Complex 2 also shows similar enhancement of its NMR spectra when it is irradiated under p-H(2). We report the use of thi...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5363785/ https://www.ncbi.nlm.nih.gov/pubmed/28451144 http://dx.doi.org/10.1039/c6sc01956k |