Quantitation of the THF Content in Fe[N(SiMe(3))(2)](2)·xTHF

[Image: see text] The absence of residual solvent in metal precursors can be of key importance for the successful preparation of metal complexes or materials. Herein, we describe methods for the quantitation of residual coordinated tetrahydrofuran (THF) that binds to Fe[N(SiMe(3))(2)](2), a commonly...

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Autores principales: Broere, Daniël L. J., Čorić, Ilija, Brosnahan, Anna, Holland, Patrick L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5363886/
https://www.ncbi.nlm.nih.gov/pubmed/28248496
http://dx.doi.org/10.1021/acs.inorgchem.7b00056
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author Broere, Daniël L. J.
Čorić, Ilija
Brosnahan, Anna
Holland, Patrick L.
author_facet Broere, Daniël L. J.
Čorić, Ilija
Brosnahan, Anna
Holland, Patrick L.
author_sort Broere, Daniël L. J.
collection PubMed
description [Image: see text] The absence of residual solvent in metal precursors can be of key importance for the successful preparation of metal complexes or materials. Herein, we describe methods for the quantitation of residual coordinated tetrahydrofuran (THF) that binds to Fe[N(SiMe(3))(2)](2), a commonly used iron synthon, when prepared according to common literature procedures. A simple method for quantitation of the amount of residual coordinated THF using (1)H NMR spectroscopy is highlighted. Finally, a detailed synthetic procedure is described for the synthesis of THF-free Fe[N(SiMe(3))(2)](2).
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spelling pubmed-53638862017-03-24 Quantitation of the THF Content in Fe[N(SiMe(3))(2)](2)·xTHF Broere, Daniël L. J. Čorić, Ilija Brosnahan, Anna Holland, Patrick L. Inorg Chem [Image: see text] The absence of residual solvent in metal precursors can be of key importance for the successful preparation of metal complexes or materials. Herein, we describe methods for the quantitation of residual coordinated tetrahydrofuran (THF) that binds to Fe[N(SiMe(3))(2)](2), a commonly used iron synthon, when prepared according to common literature procedures. A simple method for quantitation of the amount of residual coordinated THF using (1)H NMR spectroscopy is highlighted. Finally, a detailed synthetic procedure is described for the synthesis of THF-free Fe[N(SiMe(3))(2)](2). American Chemical Society 2017-03-01 2017-03-20 /pmc/articles/PMC5363886/ /pubmed/28248496 http://dx.doi.org/10.1021/acs.inorgchem.7b00056 Text en Copyright © 2017 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Broere, Daniël L. J.
Čorić, Ilija
Brosnahan, Anna
Holland, Patrick L.
Quantitation of the THF Content in Fe[N(SiMe(3))(2)](2)·xTHF
title Quantitation of the THF Content in Fe[N(SiMe(3))(2)](2)·xTHF
title_full Quantitation of the THF Content in Fe[N(SiMe(3))(2)](2)·xTHF
title_fullStr Quantitation of the THF Content in Fe[N(SiMe(3))(2)](2)·xTHF
title_full_unstemmed Quantitation of the THF Content in Fe[N(SiMe(3))(2)](2)·xTHF
title_short Quantitation of the THF Content in Fe[N(SiMe(3))(2)](2)·xTHF
title_sort quantitation of the thf content in fe[n(sime(3))(2)](2)·xthf
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5363886/
https://www.ncbi.nlm.nih.gov/pubmed/28248496
http://dx.doi.org/10.1021/acs.inorgchem.7b00056
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