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Complete diastereodivergence in asymmetric 1,6-addition reactions enabled by minimal modification of a chiral catalyst

Catalytic systems that allow selective generation of any diastereomer of a reaction product bearing multiple stereocentres through minimal modification of a single catalyst scaffold remain elusive, particularly for carbon–carbon bond formations requiring simultaneous control of multiple selectivity...

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Detalles Bibliográficos
Autores principales: Uraguchi, Daisuke, Yoshioka, Ken, Ooi, Takashi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5364390/
https://www.ncbi.nlm.nih.gov/pubmed/28317928
http://dx.doi.org/10.1038/ncomms14793