Cargando…
Complete diastereodivergence in asymmetric 1,6-addition reactions enabled by minimal modification of a chiral catalyst
Catalytic systems that allow selective generation of any diastereomer of a reaction product bearing multiple stereocentres through minimal modification of a single catalyst scaffold remain elusive, particularly for carbon–carbon bond formations requiring simultaneous control of multiple selectivity...
Autores principales: | Uraguchi, Daisuke, Yoshioka, Ken, Ooi, Takashi |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2017
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5364390/ https://www.ncbi.nlm.nih.gov/pubmed/28317928 http://dx.doi.org/10.1038/ncomms14793 |
Ejemplares similares
-
Diastereodivergent chiral aldehyde catalysis for asymmetric 1,6-conjugated addition and Mannich reactions
por: Wen, Wei, et al.
Publicado: (2020) -
Diastereodivergent organocatalysis for the asymmetric synthesis of chiral annulated furans
por: Verrier, Charlie, et al.
Publicado: (2015) -
Water enables diastereodivergency in bispidine-based chiral amine-catalyzed asymmetric Mannich reaction of cyclic N-sulfonyl ketimines with ketones
por: Li, Gonglin, et al.
Publicado: (2022) -
Chiral ammonium betaine-catalyzed asymmetric Mannich-type reaction of oxindoles
por: Torii, Masahiro, et al.
Publicado: (2016) -
Diastereodivergent asymmetric Michael-alkylation reactions using chiral N,N′-dioxide/metal complexes
por: Kuang, Yulong, et al.
Publicado: (2017)