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Mild, Redox-Neutral Alkylation of Imines Enabled by an Organic Photocatalyst
[Image: see text] An operationally simple, mild, redox-neutral method for the photoredox alkylation of imines is reported. Utilizing an inexpensive organic photoredox catalyst, alkyl radicals are readily generated from the single-electron oxidation of ammonium alkyl bis(catecholato)silicates and are...
Autores principales: | Patel, Niki R., Kelly, Christopher B., Siegenfeld, Allison P., Molander, Gary A. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5369175/ https://www.ncbi.nlm.nih.gov/pubmed/28367354 http://dx.doi.org/10.1021/acscatal.6b03665 |
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