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CO/CO and NO/NO coupling at a hidden frustrated Lewis pair template
N-Allyltetramethylpiperidine is readily isomerized to the corresponding enamine by treatment with catalytic amounts of B(C(6)F(5))(3). It adds HB(C(6)F(5))(2) at the nucleophilic enamine carbon atom to form a C/B Lewis adduct. This reacts with two molar equivalents of carbon monoxide by selective he...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5369402/ https://www.ncbi.nlm.nih.gov/pubmed/28451352 http://dx.doi.org/10.1039/c6sc04459j |