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Regioselective Carbohydrate Oxidations: A Nuclear Magnetic Resonance (NMR) Study on Selectivity, Rate, and Side-Product Formation

[Image: see text] Palladium/neocuproine catalyzed oxidation of glucosides shows an excellent selectivity for the C3-OH, but in mannosides and galactosides, unselective oxidation was initially observed. For further application in more-complex (oligo)saccharides, a better understanding of the reaction...

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Detalles Bibliográficos
Autores principales:	Eisink, Niek N. H. M., Witte, Martin D., Minnaard, Adriaan J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2017
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5370080/ https://www.ncbi.nlm.nih.gov/pubmed/28367353 http://dx.doi.org/10.1021/acscatal.6b03459

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