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Mechanistic insights on the Pd-catalyzed addition of C–X bonds across alkynes – a combined experimental and computational study
The Pd-catalyzed intramolecular addition of carbamoyl chlorides and aryl halides across alkynes is investigated by means of DFT calculations and mechanistic test experiments. The data suggest a mechanistic pathway that involves oxidative addition, alkyne insertion, cis → trans isomerization and redu...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5376711/ https://www.ncbi.nlm.nih.gov/pubmed/28451357 http://dx.doi.org/10.1039/c6sc05001h |