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Acid/base triggered interconversion of μ-η(2):η(2)-peroxido and bis(μ-oxido) dicopper intermediates capped by proton-responsive ligands

CuII2(μ-η(2):η(2)-peroxido) and CuIII2(μ-oxido)(2) cores represent key intermediates in copper/dioxygen chemistry, and they are mechanistically important for biological hydroxylation and oxidation reactions mediated by dinuclear (type III) copper metalloenzymes. While the exact nature of the active...

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Detalles Bibliográficos
Autores principales:	Goswami, V. E., Walli, A., Förster, M., Dechert, S., Demeshko, S., Holthausen, M. C., Meyer, F.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5380878/ https://www.ncbi.nlm.nih.gov/pubmed/28451371 http://dx.doi.org/10.1039/c6sc04820j

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