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Rhodium(i)-catalyzed stereoselective [4+2] cycloaddition of oxetanols with alkynes through C(sp(3))–C(sp(3)) bond cleavage
An efficient and convenient synthesis of highly functionalized dihydropyrans has been achieved through rhodium(i)-catalysed tandem C(sp(3))–C(sp(3)) bond cleavage and annulation of oxetanols with alkynes. An enantioselective version was enabled using a Binaphine ligand. Excellent site-selectivity an...
Autores principales: | Guo, Rui, Zheng, Xinxin, Zhang, Dayong, Zhang, Guozhu |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5380880/ https://www.ncbi.nlm.nih.gov/pubmed/28451367 http://dx.doi.org/10.1039/c6sc05246k |
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