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A tendril perversion in a helical oligomer: trapping and characterizing a mobile screw-sense reversal

Helical oligomers of achiral monomers adopt domains of uniform screw sense, which are occasionally interrupted by screw-sense reversals. These rare, elusive, and fast-moving features have eluded detailed characterization. We now describe the structure and habits of a screw-sense reversal trapped wit...

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Detalles Bibliográficos
Autores principales: Tomsett, Michael, Maffucci, Irene, Le Bailly, Bryden A. F., Byrne, Liam, Bijvoets, Stefan M., Lizio, M. Giovanna, Raftery, James, Butts, Craig P., Webb, Simon J., Contini, Alessandro, Clayden, Jonathan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5380885/
https://www.ncbi.nlm.nih.gov/pubmed/28451368
http://dx.doi.org/10.1039/c6sc05474a