Cargando…

Unravelling the mechanisms of vibrational relaxation in solution

We present a systematic study of the mode-specific vibrational relaxation of NO(2) in six weakly-interacting solvents (perfluorohexane, perfluoromethylcyclohexane, perfluorodecalin, carbon tetrachloride, chloroform, and d-chloroform), chosen to elucidate the dominant energy transfer mechanisms in th...

Descripción completa

Detalles Bibliográficos
Autores principales:	Grubb, Michael P., Coulter, Philip M., Marroux, Hugo J. B., Orr-Ewing, Andrew J., Ashfold, Michael N. R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5380915/ https://www.ncbi.nlm.nih.gov/pubmed/28451375 http://dx.doi.org/10.1039/c6sc05234g

Ejemplares similares

Effects of ring-strain on the ultrafast photochemistry of cyclic ketones
por: Kao, Min-Hsien, et al.
Publicado: (2020)

Vibrational Excitation of Both Products of the Reaction of CN Radicals with Acetone in Solution
por: Dunning, Greg T., et al.
Publicado: (2015)

Spin states, vibrations and spin relaxation in molecular nanomagnets and spin qubits: a critical perspective
por: Escalera-Moreno, Luis, et al.
Publicado: (2018)

Design of high-temperature f-block molecular nanomagnets through the control of vibration-induced spin relaxation
por: Escalera-Moreno, Luis, et al.
Publicado: (2019)

Nuclear Spin Relaxation of Longitudinal and Singlet Order in Liquid-CO(2) Solutions
por: Moysiadi, Aliki, et al.
Publicado: (2021)

Unravelling the antimicrobial activity of peptide hydrogel systems: current and future perspectives
por: Cross, Emily R., et al.
Publicado: (2021)

Probing the electronic structure and photophysics of thiophene–diketopyrrolopyrrole derivatives in solution
por: Polak, Daniel W., et al.
Publicado: (2022)

Hydroxy-bridged resting states of a [NiFe]-hydrogenase unraveled by cryogenic vibrational spectroscopy and DFT computations
por: Caserta, Giorgio, et al.
Publicado: (2020)

The Role of Norrish Type-I Chemistry in Photoactive Drugs: An ab initio Study of a Cyclopropenone-Enediyne Drug Precursor
por: Léger, Spencer J., et al.
Publicado: (2020)

Unraveling the reaction mechanisms for furfural electroreduction on copper
por: Liu, Sihang, et al.
Publicado: (2023)

Mapping the multi-step mechanism of a photoredox catalyzed atom-transfer radical polymerization reaction by direct observation of the reactive intermediates
por: Lewis-Borrell, Luke, et al.
Publicado: (2020)

Quantifying rival bond fission probabilities following photoexcitation: C–S bond fission in t-butylmethylsulfide
por: Bain, Matthew, et al.
Publicado: (2019)

Introducing carbon dots to moderate the blue emission from zinc vanadium oxide hydroxide hydrate nanoplates
por: Huang, Peng, et al.
Publicado: (2018)

Transient absorption spectroscopy of the electron transfer step in the photochemically activated polymerizations of N-ethylcarbazole and 9-phenylcarbazole
por: Thornton, Georgia L., et al.
Publicado: (2021)

Electronic transitions of molecules: vibrating Lewis structures
por: Liu, Yu, et al.
Publicado: (2019)

Unconventional two-step spin relaxation dynamics of [Re(CO)(3)(im)(phen)](+) in aqueous solution
por: Mai, Sebastian, et al.
Publicado: (2019)

Accelerated Vibrational Energy Relaxation of Water in Alkaline Environments
por: Cota, Roberto, et al.
Publicado: (2021)

Vibrational Stark shift spectroscopy of catalysts under the influence of electric fields at electrode–solution interfaces
por: Bhattacharyya, Dhritiman, et al.
Publicado: (2021)

Enantioselective one-carbon expansion of aromatic rings by simultaneous formation and chromoselective irradiation of a transient coloured enolate
por: Saunthwal, Rakesh K., et al.
Publicado: (2022)

Correction: The structural, vibrational, and mechanical properties of jammed packings of deformable particles in three dimensions
por: Wang, Dong, et al.
Publicado: (2022)

Unraveling the mechanism of CO(2) capture and separation by porous liquids
por: Yin, Jie, et al.
Publicado: (2020)

Tailoring relaxation dynamics and mechanical memory of crumpled materials by friction and ductility
por: van Bruggen, Eric, et al.
Publicado: (2019)

Carbon Nanomaterials: A New Sustainable Solution to Reduce the Emerging Environmental Pollution of Turbomachinery Noise and Vibration
por: Jia, Xiao Qi, et al.
Publicado: (2020)

Editorial: Vibrationally-Mediated Chemical Dynamics
por: Dean, Jacob C., et al.
Publicado: (2021)

Charge-Separated Reactive Intermediates from the UV Photodissociation of Chlorobenzene in Solution
por: Kao, Min-Hsien, et al.
Publicado: (2022)

Unraveling the catalytic mechanisms of H(2) production with thiosemicarbazone nickel complexes
por: Barrozo, Alexandre, et al.
Publicado: (2021)

Vibrational circular dichroism spectroscopy for probing the expression of chirality in mechanically planar chiral rotaxanes
por: Koenis, Mark A. J., et al.
Publicado: (2020)

Chemoenzymatic elaboration of the Raper–Mason pathway unravels the structural diversity within eumelanin pigments
por: Ni, Qing Zhe, et al.
Publicado: (2020)

Wavelength dependent mechanism of phenolate photooxidation in aqueous solution
por: Robertson, Kate, et al.
Publicado: (2023)

Unraveling the kinetics and molecular mechanism of gas phase pyrolysis of cubane to [8]annulene
por: Seif, Ahmad, et al.
Publicado: (2020)

Unravelling the fibrillation mechanism of ovalbumin in the presence of mercury at its isoelectric pH
por: Mathew, Manjumol, et al.
Publicado: (2020)

Stress relaxation in tunable gels
por: Raffaelli, Chiara, et al.
Publicado: (2021)

Modified relaxation dynamics and coherent energy exchange in coupled vibration-cavity polaritons
por: Dunkelberger, A. D., et al.
Publicado: (2016)

Unravelling moisture-induced CO(2) chemisorption mechanisms in amine-modified sorbents at the molecular scale
por: Sardo, Mariana, et al.
Publicado: (2021)

Slow magnetic relaxation in octahedral low-spin Ni(iii) complexes
por: Bhowmick, Indrani, et al.
Publicado: (2018)

Unraveling the microstructural and optoelectronic properties of solution-processed Pr-doped SrSnO(3) perovskite oxide thin films
por: Shaili, Hamza, et al.
Publicado: (2021)

Unravelling the true MOF-5 luminescence
por: Villemot, Vincent, et al.
Publicado: (2020)

Unravelling the enigma of lignin(OX): can the oxidation of lignin be controlled?
por: Guo, Haiwei, et al.
Publicado: (2017)

Characterisation of magnetic relaxation on extremely long timescales
por: Blackmore, William J. A., et al.
Publicado: (2023)

Vibrational Relaxation Dynamics of the Core and Outer Part of Proton-Hydration Clusters
por: Sofronov, Oleksandr O., et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_h162jnrmdg146aani75s6t66jm