Synthesis and crystal structure of bis­(μ-2-methyl­benzene­thiol­ato-κ(2) S:S)bis­[meth­yl(2-methyl­benzene­thiol­ato-κS)indium(III)]

The dinuclear title compound, [In(2)(CH(3))(2)(C(7)H(7)S)(4)] or [Me(2-MeC(6)H(4)S)In-μ-(2-MeC(6)H(4)S)(2)InMe(2-MeC(6)H(4)S)], was prepared from the 1:2 reaction of Me(3)In and 2-MeC(6)H(4)SH in toluene. Its crystal structure exhibits a four-membered In(2)S(2) ring core via bridging (2-MeC(6)H(4)S)...

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Autores principales: Briand, Glen G., Decken, Andreas, Dickie, Courtney M., MacNeil, Gregory
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382603/
https://www.ncbi.nlm.nih.gov/pubmed/28435702
http://dx.doi.org/10.1107/S2056989017003498
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author Briand, Glen G.
Decken, Andreas
Dickie, Courtney M.
MacNeil, Gregory
author_facet Briand, Glen G.
Decken, Andreas
Dickie, Courtney M.
MacNeil, Gregory
author_sort Briand, Glen G.
collection PubMed
description The dinuclear title compound, [In(2)(CH(3))(2)(C(7)H(7)S)(4)] or [Me(2-MeC(6)H(4)S)In-μ-(2-MeC(6)H(4)S)(2)InMe(2-MeC(6)H(4)S)], was prepared from the 1:2 reaction of Me(3)In and 2-MeC(6)H(4)SH in toluene. Its crystal structure exhibits a four-membered In(2)S(2) ring core via bridging (2-MeC(6)H(4)S) groups. The dimeric units are further associated into a one-dimensional polymeric structure extending parallel to the a axis via inter­molecular In⋯S contacts. The In atoms are then in distorted trigonal–bipyramidal CS(4) bonding environments.
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spelling pubmed-53826032017-04-21 Synthesis and crystal structure of bis­(μ-2-methyl­benzene­thiol­ato-κ(2) S:S)bis­[meth­yl(2-methyl­benzene­thiol­ato-κS)indium(III)] Briand, Glen G. Decken, Andreas Dickie, Courtney M. MacNeil, Gregory Acta Crystallogr E Crystallogr Commun Research Communications The dinuclear title compound, [In(2)(CH(3))(2)(C(7)H(7)S)(4)] or [Me(2-MeC(6)H(4)S)In-μ-(2-MeC(6)H(4)S)(2)InMe(2-MeC(6)H(4)S)], was prepared from the 1:2 reaction of Me(3)In and 2-MeC(6)H(4)SH in toluene. Its crystal structure exhibits a four-membered In(2)S(2) ring core via bridging (2-MeC(6)H(4)S) groups. The dimeric units are further associated into a one-dimensional polymeric structure extending parallel to the a axis via inter­molecular In⋯S contacts. The In atoms are then in distorted trigonal–bipyramidal CS(4) bonding environments. International Union of Crystallography 2017-03-10 /pmc/articles/PMC5382603/ /pubmed/28435702 http://dx.doi.org/10.1107/S2056989017003498 Text en © Briand et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Briand, Glen G.
Decken, Andreas
Dickie, Courtney M.
MacNeil, Gregory
Synthesis and crystal structure of bis­(μ-2-methyl­benzene­thiol­ato-κ(2) S:S)bis­[meth­yl(2-methyl­benzene­thiol­ato-κS)indium(III)]
title Synthesis and crystal structure of bis­(μ-2-methyl­benzene­thiol­ato-κ(2) S:S)bis­[meth­yl(2-methyl­benzene­thiol­ato-κS)indium(III)]
title_full Synthesis and crystal structure of bis­(μ-2-methyl­benzene­thiol­ato-κ(2) S:S)bis­[meth­yl(2-methyl­benzene­thiol­ato-κS)indium(III)]
title_fullStr Synthesis and crystal structure of bis­(μ-2-methyl­benzene­thiol­ato-κ(2) S:S)bis­[meth­yl(2-methyl­benzene­thiol­ato-κS)indium(III)]
title_full_unstemmed Synthesis and crystal structure of bis­(μ-2-methyl­benzene­thiol­ato-κ(2) S:S)bis­[meth­yl(2-methyl­benzene­thiol­ato-κS)indium(III)]
title_short Synthesis and crystal structure of bis­(μ-2-methyl­benzene­thiol­ato-κ(2) S:S)bis­[meth­yl(2-methyl­benzene­thiol­ato-κS)indium(III)]
title_sort synthesis and crystal structure of bis­(μ-2-methyl­benzene­thiol­ato-κ(2) s:s)bis­[meth­yl(2-methyl­benzene­thiol­ato-κs)indium(iii)]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382603/
https://www.ncbi.nlm.nih.gov/pubmed/28435702
http://dx.doi.org/10.1107/S2056989017003498
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