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Synthesis and crystal structure of bis­(μ-2-methyl­benzene­thiol­ato-κ(2) S:S)bis­[meth­yl(2-methyl­benzene­thiol­ato-κS)indium(III)]

The dinuclear title compound, [In(2)(CH(3))(2)(C(7)H(7)S)(4)] or [Me(2-MeC(6)H(4)S)In-μ-(2-MeC(6)H(4)S)(2)InMe(2-MeC(6)H(4)S)], was prepared from the 1:2 reaction of Me(3)In and 2-MeC(6)H(4)SH in toluene. Its crystal structure exhibits a four-membered In(2)S(2) ring core via bridging (2-MeC(6)H(4)S)...

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Detalles Bibliográficos
Autores principales: Briand, Glen G., Decken, Andreas, Dickie, Courtney M., MacNeil, Gregory
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382603/
https://www.ncbi.nlm.nih.gov/pubmed/28435702
http://dx.doi.org/10.1107/S2056989017003498